Self-Assembly of Molecular Borromean Rings from Bimetallic Coordination Rectangles†
Sheng-Li Huang
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)
Search for more papers by this authorYue-Jian Lin
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)
Search for more papers by this authorZhen-Hua Li
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Guo-Xin Jin
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)Search for more papers by this authorSheng-Li Huang
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)
Search for more papers by this authorYue-Jian Lin
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)
Search for more papers by this authorZhen-Hua Li
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Guo-Xin Jin
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)
State Key Laboratory of Molecular Engineering of Polymers, Department of Chemistry, Fudan University, 220 Handan road, Shanghai, 200433 (P. R. China)Search for more papers by this authorThis work was supported by the National Science Foundation of China (91122017, 21374019), the Program for Changjiang Scholars and Innovative Research Team in University (IRT1117), and the Shanghai Science and Technology Committee (13JC1400600, 13DZ2275200).
Abstract
In contrast to conventional stepwise synthesis of molecular Borromean rings, a self-assembly synthetic method which proceeds without the aid of a template has been developed. In the formation of molecular rectangles, by adjustment of the long-arm length of the rectangles, a series of size-dependent Borromean-link frameworks were constructed. Both the shortest length of two arms and the relative proportion of the length of the long arm to that of the short arm play a key role in the formation of Borromean rings. DFT calculations were used to provide theoretical support for the formation of discrete interlocked frameworks.
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