Volume 125, Issue 43 pp. 11607-11611

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Nitril-Nitril-C-C-Kupplungen an Gruppe-4-Metallocenen zu 1-Metalla-2,5-diazacyclopenta-2,4-dienen und deren Reaktionen^†

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Dipl.-Chem. Lisanne Becker,

Dipl.-Chem. Lisanne Becker

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

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Dr. Perdita Arndt,

Dr. Perdita Arndt

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

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Dr. Haijun Jiao,

Dr. Haijun Jiao

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

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Dr. Anke Spannenberg,

Dr. Anke Spannenberg

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

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Prof. Dr. Uwe Rosenthal,

Corresponding Author

Prof. Dr. Uwe Rosenthal

[email protected]

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)Search for more papers by this author

Dipl.-Chem. Lisanne Becker,

Dipl.-Chem. Lisanne Becker

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

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Dr. Perdita Arndt,

Dr. Perdita Arndt

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

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Dr. Haijun Jiao,

Dr. Haijun Jiao

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

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Dr. Anke Spannenberg,

Dr. Anke Spannenberg

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

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Prof. Dr. Uwe Rosenthal,

Corresponding Author

Prof. Dr. Uwe Rosenthal

[email protected]

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Deutschland)Search for more papers by this author

First published: 11 September 2013

https://doi.org/10.1002/ange.201303748

Citations: 19

^†

Wir danken der Deutschen Forschungsgemeinschaft (RO 1269/8-1) für die finanzielle Unterstützung.

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Graphical Abstract

Die C-C-Kupplung von Arylnitrilen an Gruppe-4-Metallocene liefert ungewöhnliche 1-Metalla-2,5-diazacyclopenta-2,4-diene, deren strukturelle, energetische und chemische Eigenschaften untersucht wurden. Die Reaktionen dieser Verbindungen mit CH₃CN, H₂, CO₂ und HCl führten in den meisten Fällen zur Freisetzung eines Nitrils und dem Einbau eines zweiten Substrats an dessen Stelle.

Supporting Information

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Nitril-Nitril-C-C-Kupplungen an Gruppe-4-Metallocenen zu 1-Metalla-2,5-diazacyclopenta-2,4-dienen und deren Reaktionen^†

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Berichtigung: Nitril-Nitril-C-C-Kupplungen an Gruppe-4-Metallocenen zu 1-Metalla-2,5-diazacyclopenta-2,4-dienen und deren Reaktionen

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Nitril-Nitril-C-C-Kupplungen an Gruppe-4-Metallocenen zu 1-Metalla-2,5-diazacyclopenta-2,4-dienen und deren Reaktionen†

Correction(s) for this article

Berichtigung: Nitril-Nitril-C-C-Kupplungen an Gruppe-4-Metallocenen zu 1-Metalla-2,5-diazacyclopenta-2,4-dienen und deren Reaktionen

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Nitril-Nitril-C-C-Kupplungen an Gruppe-4-Metallocenen zu 1-Metalla-2,5-diazacyclopenta-2,4-dienen und deren Reaktionen^†