Direct Observation of Cyclic Carbenium Ions and Their Role in the Catalytic Cycle of the Methanol-to-Olefin Reaction over Chabazite Zeolites†
Dr. Shutao Xu
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
These authors contributed equally to this work.
Search for more papers by this authorProf. Dr. Anmin Zheng
State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (P. R. China)
These authors contributed equally to this work.
Search for more papers by this authorProf. Dr. Yingxu Wei
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorJingrun Chen
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorDr. Jinzhe Li
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorYueying Chu
State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (P. R. China)
Search for more papers by this authorMozhi Zhang
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorQuanyi Wang
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorYou Zhou
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorJinbang Wang
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorProf. Dr. Feng Deng
State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Zhongmin Liu
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)Search for more papers by this authorDr. Shutao Xu
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
These authors contributed equally to this work.
Search for more papers by this authorProf. Dr. Anmin Zheng
State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (P. R. China)
These authors contributed equally to this work.
Search for more papers by this authorProf. Dr. Yingxu Wei
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorJingrun Chen
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorDr. Jinzhe Li
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorYueying Chu
State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (P. R. China)
Search for more papers by this authorMozhi Zhang
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorQuanyi Wang
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorYou Zhou
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorJinbang Wang
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
Search for more papers by this authorProf. Dr. Feng Deng
State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (P. R. China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Zhongmin Liu
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)
National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (P. R. China)Search for more papers by this authorWe are grateful for the financial support of the National Natural Science Foundation of China (No. 21073228, 21173255, 21103180, 21273230, and 21273005). We gratefully thank Dr. Fan Yang for fruitful discussions.
Graphical Abstract
Carbeniumionen in Zeolithen: Mit 13C-NMR-Spektroskopie wurden erstmals zwei wichtige Carbeniumionen unter Bedingungen der Methanol-zu-Olefin(MTO)-Reaktion über Chabazit-Zeolithen beobachtet. Die entscheidenden Rollen dieser Ionen im MTO-Zyklus wurden mithilfe kombinierter experimenteller und theoretischer Studien aufgezeigt.
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