Volume 125, Issue 8 p. 2432
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Rücktitelbild: Pulling the Levers of Photophysics: How Structure Controls the Rate of Energy Dissipation (Angew. Chem. 8/2013)

Thomas S. Kuhlman

Thomas S. Kuhlman

Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)

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Prof. Michael Pittelkow

Prof. Michael Pittelkow

Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)

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Prof. Theis I. Sølling

Corresponding Author

Prof. Theis I. Sølling

Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)

Theis I. Sølling, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)===

Klaus B. Møller, Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)===

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Prof. Klaus B. Møller

Corresponding Author

Prof. Klaus B. Møller

Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)

Theis I. Sølling, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 København Ø (Denmark)===

Klaus B. Møller, Department of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby (Denmark)===

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First published: 25 January 2013

Graphical Abstract

Mithilfe zeitauflösender Femtosekunden-Spektroskopie kann der interne Konversionsprozess unter einem neuen Blickwinkel betrachtet werden. In ihrer Zuschrift auf Seite 2303 ff. zeigen T. I. Sølling, K. B. Møller et al., dass der S2-S1-Übergang einer Reihe cyclischer Ketone durch sehr wenige Freiheitsgrade herbeigeführt wird. Dieses Wissen macht es möglich, die Übergangsdynamik vorherzusagen und durch Modifizieren der Molekülstruktur zu beeinflussen.

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