Facile Carbon Monoxide Reduction at Intramolecular Frustrated Phosphane/Borane Lewis Pair Templates†
Dr. Muhammad Sajid
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorLisa-Maria Elmer
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorChristoph Rosorius
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorDr. Constantin G. Daniliuc
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorProf. Dr. Stefan Grimme
Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Beringstraße 4, 53115 Bonn (Germany)
Search for more papers by this authorDr. Gerald Kehr
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Gerhard Erker
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)===Search for more papers by this authorDr. Muhammad Sajid
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorLisa-Maria Elmer
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorChristoph Rosorius
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorDr. Constantin G. Daniliuc
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorProf. Dr. Stefan Grimme
Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Beringstraße 4, 53115 Bonn (Germany)
Search for more papers by this authorDr. Gerald Kehr
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Gerhard Erker
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)
Organisch-Chemisches Institut der Universität Münster, Corrensstraße 40, 48149 Münster (Germany)===Search for more papers by this authorFinancial Support from the European Research Council and the Deutsche Forschungsgemeinschaft is gratefully acknowledged.
Graphical Abstract
Ein neuer Reaktionspfad: Kohlenmonoxid wird leicht mit Piers' Boran und einem frustrierten Lewis-Paar (FLP) zu einem FLP-stabilisierten Formylboran reduziert (siehe Bild). Diese Reaktion kann als ein typisches Beispiel für die effiziente Aktivierung eines kleinen Moleküls durch ein FLP betrachtet werden.
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- 14One can easily formulate alternative CO reduction pathways. A referee suggested potential carbon monoxide reduction at a preformed FLP–CO adduct as an alternative. We have found indications that both the FLPs 4 and 6 indeed form CO adducts, but both are thermally rather unstable and loose the CO molecule above −20 °C (M. Sajid, W. Dong, G. Kehr, G. Erker, unpublished).
- 15CCDC 916134 (2), CCDC 916135 (5), and CCDC 916136 (7) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Center via www.ccdc.cam.ac.uk/data_request/cif.
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