High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation†
Corresponding Author
Dr. Matteo Ceppatelli
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy)
LENS, European Laboratory for Non-Linear Spectroscopy, Firenze (Italy)
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy)===Search for more papers by this authorProf. Roberto Bini
LENS, European Laboratory for Non-Linear Spectroscopy, Firenze (Italy)
Dipartimento di Chimica “Ugo Schiff”, Università degli Studi di Firenze (Italy)
Search for more papers by this authorDr. Maria Caporali
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy)
Search for more papers by this authorDr. Maurizio Peruzzini
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy)
Search for more papers by this authorCorresponding Author
Dr. Matteo Ceppatelli
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy)
LENS, European Laboratory for Non-Linear Spectroscopy, Firenze (Italy)
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy)===Search for more papers by this authorProf. Roberto Bini
LENS, European Laboratory for Non-Linear Spectroscopy, Firenze (Italy)
Dipartimento di Chimica “Ugo Schiff”, Università degli Studi di Firenze (Italy)
Search for more papers by this authorDr. Maria Caporali
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy)
Search for more papers by this authorDr. Maurizio Peruzzini
ICCOM-CNR, Istituto di Chimica dei Composti OrganoMetallici, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Firenze (Italy)
Search for more papers by this authorThis work was supported by the European Union under Contract RII3-CT2003-506350, given by the Italian Ministero dell’Università e della Ricerca Scientifica e Tecnologica (MURST), and by “Firenze Hydrolab” through a grant by Ente Cassa di Risparmio di Firenze.
Graphical Abstract
Unter Hochdruckbedingungen, in einer Diamant-Stempelzelle, löst die Bestrahlung von rotem Phosphor (orange im Schema) und Wasser eine Reaktion aus, die H2, PH3, H3PO2, H3PO4 und H3PO4 liefert (H grau, O rot, P orange). Die Reaktion lässt sich mithilfe der Raman-Spektroskopie einfach verfolgen.
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