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Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Preinstalled CH₃NCS^†

Dr. Yasuhide Inokuma

Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

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Guo-Hong Ning,

Guo-Hong Ning

Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

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Prof. Dr. Makoto Fujita,

Corresponding Author

Prof. Dr. Makoto Fujita

[email protected]

Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)Search for more papers by this author

Dr. Yasuhide Inokuma,

Dr. Yasuhide Inokuma

Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

Search for more papers by this author

Guo-Hong Ning,

Guo-Hong Ning

Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

Search for more papers by this author

Prof. Dr. Makoto Fujita,

Corresponding Author

Prof. Dr. Makoto Fujita

[email protected]

Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)Search for more papers by this author

First published: 19 January 2012

https://doi.org/10.1002/ange.201107190

Citations: 4

^†

This research was supported by the CREST project of the Japan Science and Technology Agency (JST), for which M.F. is the principal investigator, and also in part by KAKENHI (20044006), JSPS, and Global COE Program (Chemistry Innovation through Cooperation of Science and Engineering), MEXT (Japan). Y.I. thanks Kurata Grants for younger scientists.

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Graphical Abstract

Kristalline Reagenskapseln wurden durch Einbringen von CH₃NCS in vernetzte molekulare Kapseln erzeugt. Die feste Verkapselung verhindert zunächst ein Auslaugen von Reagensmolekülen in die Lösung, und erst beim Eindringen von Aminen in die interstitiellen Poren wird das Reagens freigesetzt. Das Ergebnis ist eine gesteigerte Substratselektivität in der Festkörper-Thiocarbamoylierung (siehe Bild; 86:14 zugunsten von 2- gegenüber 1-Naphthylamin).

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Volume124, Issue10

March 5, 2012

Pages 2429-2431

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Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Preinstalled CH₃NCS^†

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Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Preinstalled CH3NCS†

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Reagent-Installed Capsule Network: Selective Thiocarbamoylation of Aromatic Amines in Crystals with Preinstalled CH₃NCS^†