Controlling the Nucleation and Growth of Silver on Palladium Nanocubes by Manipulating the Reaction Kinetics†
Dr. Jie Zeng
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Search for more papers by this authorCun Zhu
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Search for more papers by this authorDr. Jing Tao
Condensed Matter Physics & Materials Science Department, Brookhaven National Laboratory, Upton, NY 11973 (USA)
Search for more papers by this authorMingshang Jin
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Search for more papers by this authorDr. Hui Zhang
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Search for more papers by this authorDr. Zhi-Yuan Li
Institute of Physics, Chinese Academy of Sciences, Beijing 100080 (P. R. China)
Search for more papers by this authorDr. Yimei Zhu
Condensed Matter Physics & Materials Science Department, Brookhaven National Laboratory, Upton, NY 11973 (USA)
Search for more papers by this authorCorresponding Author
Prof. Younan Xia
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)Search for more papers by this authorDr. Jie Zeng
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Search for more papers by this authorCun Zhu
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Search for more papers by this authorDr. Jing Tao
Condensed Matter Physics & Materials Science Department, Brookhaven National Laboratory, Upton, NY 11973 (USA)
Search for more papers by this authorMingshang Jin
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Search for more papers by this authorDr. Hui Zhang
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Search for more papers by this authorDr. Zhi-Yuan Li
Institute of Physics, Chinese Academy of Sciences, Beijing 100080 (P. R. China)
Search for more papers by this authorDr. Yimei Zhu
Condensed Matter Physics & Materials Science Department, Brookhaven National Laboratory, Upton, NY 11973 (USA)
Search for more papers by this authorCorresponding Author
Prof. Younan Xia
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)
Department of Biomedical Engineering, Washington University, St. Louis, MO 63130 (USA)Search for more papers by this authorThis work was supported in part by grants from the NSF (DMR, 0804088 and 1104616) and startup funds from Washington University in St. Louis. Y.X. was also partially supported by the World Class University (WCU) program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology (R32-20031). Part of the research was performed at the Nano Research Facility (NRF), a member of the National Nanotechnology Infrastructure Network (NNIN), which is funded by the NSF under award no. ECS-0335765. The work at BNL was supported by the U.S. Department of Energy, Basic Energy Sciences, by the Materials Sciences and Engineering Division under Contract No. DE-AC02-98CH10886 and through the use of CFN.
Graphical Abstract
Routenplanung für Atome: Über die Geschwindigkeit, mit der Ag-Atome aus einer Vorstufe erzeugt wurden, wurden die Keimbildung und das Wachstum von Ag auf Pd-Nanowürfeln mit sechs äquivalenten {100}-Seiten gesteuert. Drei Arten von Dimetall-Nanokristallen wurden erhalten: hybride Pd-Ag-Dimere, exzentrische Pd-Ag-Nanostäbe und Pd@Ag-Kern-Schale-Nanokristalle (siehe Schema).
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