Morphology Control of Polymer Particles in Ethylene/Carbon Monoxide Copolymerization†
Ji Hae Park
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorKyoung Hwan Oh
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorSung Hun Kim
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorAnish Cyriac
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorJobi Kodiyan Varghese
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorProf. Myung Whan Hwang
Department of Safety Engineering, Incheon University, Incheon 406-772 (Korea)
Search for more papers by this authorCorresponding Author
Prof. Bun Yeoul Lee
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylabSearch for more papers by this authorJi Hae Park
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorKyoung Hwan Oh
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorSung Hun Kim
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorAnish Cyriac
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorJobi Kodiyan Varghese
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Search for more papers by this authorProf. Myung Whan Hwang
Department of Safety Engineering, Incheon University, Incheon 406-772 (Korea)
Search for more papers by this authorCorresponding Author
Prof. Bun Yeoul Lee
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylab
Department of Molecular Science and Technology, Ajou University, Suwon 443-749 (Korea) http://www.ajou.ac.kr/∼polylabSearch for more papers by this authorThis work was supported by Mid-carrier Researcher Program (No. 2011-0000111) and by Priority Research Centers Program (2010-0028294) through NRF of Korea.
Graphical Abstract
Unter Druck gesetzt werden katalysatorhaltige, in Wasser dispergierte 1-Octanoltröpfchen, um so die Morphologie der Polymerpartikel bei der Ethylen/CO-Copolymerisation zu steuern. Der Pd-Katalysator sollte mit lipophilen, langen Alkylketten ausgestattet sein. Polymerpartikel mit einer Größe von 0.5–1.0 mm (siehe Aufnahmen) und Volumendichten von 0.2–0.3 g mL−1 werden ohne Reaktorverschmutzung produziert.
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