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Structural and Electrochemical Diversity in LiFe_1−δZn_δSO₄F Solid Solution: A Fe-Based 3.9 V Positive-Electrode Material^†

Mohammed Ati

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)

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Brent C. Melot,

Brent C. Melot

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)

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Gwenaëlle Rousse,

Gwenaëlle Rousse

Institut de Minéralogie, et de Physique des Milieux Condensés (IMPMC), UMR 7590 CNRS-Université Pierre, et Marie Curie (UPMC) Case courrier 115, 4 Place Jussieu, 75252 Paris Cedex 05 (France)

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Jean-Noël Chotard,

Jean-Noël Chotard

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)

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Prabeer Barpanda,

Prabeer Barpanda

Department of Chemical System Engineering, The University of Tokyo, 5-604, 7-3-1 Hongo, Bunkyo-Ku, 113-8656 Tokyo (Japan)

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Prof. Jean-Marie Tarascon,

Corresponding Author

Prof. Jean-Marie Tarascon

[email protected]

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)

Collège de France, 11 Place Marcelin Berthelot, 75005 Paris (France)

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)Search for more papers by this author

Mohammed Ati,

Mohammed Ati

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)

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Brent C. Melot,

Brent C. Melot

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)

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Gwenaëlle Rousse,

Gwenaëlle Rousse

Institut de Minéralogie, et de Physique des Milieux Condensés (IMPMC), UMR 7590 CNRS-Université Pierre, et Marie Curie (UPMC) Case courrier 115, 4 Place Jussieu, 75252 Paris Cedex 05 (France)

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Jean-Noël Chotard,

Jean-Noël Chotard

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)

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Prabeer Barpanda,

Prabeer Barpanda

Department of Chemical System Engineering, The University of Tokyo, 5-604, 7-3-1 Hongo, Bunkyo-Ku, 113-8656 Tokyo (Japan)

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Prof. Jean-Marie Tarascon,

Corresponding Author

Prof. Jean-Marie Tarascon

[email protected]

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)

Collège de France, 11 Place Marcelin Berthelot, 75005 Paris (France)

Laboratoire de Réactivité et Chimie des Solides, Université de Picardie Jules Verne, CNRS UMR 6007, 33, rue Saint Leu, 80039 Amiens (France)Search for more papers by this author

First published: 16 September 2011

https://doi.org/10.1002/ange.201104648

Citations: 6

^†

The authors are thankful to G. Ferey, C. Masquelier, M. Armand, N. Recham for helpful discussions and ALISTORE-ERI for supporting this work. P.B. thanks the Japan Society for the Promotion of Sciences for a JSPS Fellowship at the University of Tokyo.

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Graphical Abstract

Übergangsmetallhaltige Fluorsulfatverbindungen werden als Anodenmaterial für Lithiumionenbatterien intensiv untersucht. Durch den Einbau von Zn in LiFeSO₄F kann die Tavorit-Struktur in zwei verschiedene Polymorphe mit Sillimanit- und Triplit-Struktur überführt werden (siehe Bild). Diese neuen Phasen zeigen gegenüber Li Fe²⁺/Fe³⁺-Redoxpotentiale von 3.6 und 3.9 V.

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Volume123, Issue45

November 4, 2011

Pages 10762-10765

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Structural and Electrochemical Diversity in LiFe_1−δZn_δSO₄F Solid Solution: A Fe-Based 3.9 V Positive-Electrode Material^†

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Structural and Electrochemical Diversity in LiFe1−δZnδSO4F Solid Solution: A Fe-Based 3.9 V Positive-Electrode Material†

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Structural and Electrochemical Diversity in LiFe_1−δZn_δSO₄F Solid Solution: A Fe-Based 3.9 V Positive-Electrode Material^†