Ionische Flüssigkeiten als hypergole Treibstoffe
Dr. Yanqiang Zhang
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA), Fax: (+1) 208-885-9146
Search for more papers by this authorProf. Dr. Haixiang Gao
Department of Applied Chemistry, China Agricultural University, Beijing, 100083 (China)
Search for more papers by this authorDr. Young-Hyuk Joo
Department of Explosives & Pyrotechnics, Hanwha Corporation R&D Center 2-1, Woisam-Dong, Yuseong-Gu, Daejeon, 305-156 (Korea)
Search for more papers by this authorCorresponding Author
Prof. Dr. Jean'ne M. Shreeve
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA), Fax: (+1) 208-885-9146
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA), Fax: (+1) 208-885-9146Search for more papers by this authorDr. Yanqiang Zhang
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA), Fax: (+1) 208-885-9146
Search for more papers by this authorProf. Dr. Haixiang Gao
Department of Applied Chemistry, China Agricultural University, Beijing, 100083 (China)
Search for more papers by this authorDr. Young-Hyuk Joo
Department of Explosives & Pyrotechnics, Hanwha Corporation R&D Center 2-1, Woisam-Dong, Yuseong-Gu, Daejeon, 305-156 (Korea)
Search for more papers by this authorCorresponding Author
Prof. Dr. Jean'ne M. Shreeve
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA), Fax: (+1) 208-885-9146
Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA), Fax: (+1) 208-885-9146Search for more papers by this authorAbstract
Noch immer werden in Treibstoffsystemen Hydrazin und dessen Derivate als Brennstoffe eingesetzt, obwohl es sich dabei um karzinogene und toxische Substanzen handelt, die recht hohe Dampfdrücke haben und kostenintensive Sicherheitsvorkehrungen erfordern. Erst 2008 wurde entdeckt, dass sich ionische Flüssigkeiten mit Dicyanamid-Anionen beim Kontakt mit Oxidationsmitteln spontan entzünden können (Hypergolie). Solche Flüssigkeiten sind wenig flüchtig sowie thermisch und chemisch recht stabil und verfügen oft über große Flüssigkeitsbereiche, was die Anwendung in Zweikomponententreibstoffen unter vielfältigen Bedingungen ermöglichen könnte. Eine neue Familie von in Wasser synthetisierbaren Dicyanoboraten wird präsentiert, die nahezu alle Anforderungen an leistungsstarke Treibstoffe erfüllt.
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