Hydrogen Storage in Magnesium Hydride: The Molecular Approach†
Corresponding Author
Prof. Dr. Sjoerd Harder
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen (Netherlands), Fax: (+31) 50-363-4296
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen (Netherlands), Fax: (+31) 50-363-4296Search for more papers by this authorDr. Jan Spielmann
Fakultät für Chemie, Universität Duisburg-Essen, Universitätsstrasse 5, 45117 Duisburg (Germany)
Search for more papers by this authorJulia Intemann
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen (Netherlands), Fax: (+31) 50-363-4296
Search for more papers by this authorHeinz Bandmann
Fakultät für Chemie, Universität Duisburg-Essen, Universitätsstrasse 5, 45117 Duisburg (Germany)
Search for more papers by this authorCorresponding Author
Prof. Dr. Sjoerd Harder
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen (Netherlands), Fax: (+31) 50-363-4296
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen (Netherlands), Fax: (+31) 50-363-4296Search for more papers by this authorDr. Jan Spielmann
Fakultät für Chemie, Universität Duisburg-Essen, Universitätsstrasse 5, 45117 Duisburg (Germany)
Search for more papers by this authorJulia Intemann
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen (Netherlands), Fax: (+31) 50-363-4296
Search for more papers by this authorHeinz Bandmann
Fakultät für Chemie, Universität Duisburg-Essen, Universitätsstrasse 5, 45117 Duisburg (Germany)
Search for more papers by this authorWe thank the Deutsche Forschungsgemeinschaft for financial support of this project. Prof. Dr. R. Boese and D. Bläser are kindly acknowledged for collection of X-ray data.
Graphical Abstract
Groß und klein zugleich: Der größte ligandenstabilisierte Magnesiumhydridcluster, bestehend aus 8 Mg2+- und 10 H−-Ionen, dient als Modell für das kleinste Wasserstoffspeichermaterial im Subnanometerbereich. Zwischen Hydrid-Ionen in diesem molekularen Cluster werden magnetische Kopplungen beobachtet (siehe Bild), und ein Erwärmen auf lediglich 200 °C genügt, um den Wasserstoff vollständig zu desorbieren.
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