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A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides^†

Dr. Pedro Serna

Department of Chemical Engineering and Materials Science, University of California, One Shields Avenue, Davis, CA 95616 (USA), Fax: (+1) 530-752-1031 http://www.chms.ucdavis.edu/research/web/catalysis

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Prof. B. C. Gates,

Corresponding Author

Prof. B. C. Gates

[email protected]

Dr. Pedro Serna,

Dr. Pedro Serna

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Prof. B. C. Gates,

Corresponding Author

Prof. B. C. Gates

[email protected]

First published: 29 April 2011

https://doi.org/10.1002/ange.201008086

Citations: 10

^†

We acknowledge DOE Basic Energy Sciences for support (Contract No. FG02-04ER15513) and acknowledge beam time and support of the DOE Division of Materials Sciences for its role in the operation and development of beam line MR-CAT at the Advanced Photon Source at Argonne National Laboratory.

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Graphical Abstract

Keine Liganden nötig: Rhodium-Komplexe auf HY-Zeolith als Träger katalysieren die Bildung von C-C-Bindungen über einen neuartigen Mechanismus, der eine Kooperation zwischen der Metallspezies und Brønsted-Säurezentren des Zeolithträgers umfasst (siehe Bild). Der Katalysator agiert in Abwesenheit von Liganden wie Halogeniden und zeigt eine hohe Selektivität für n-Butene, sogar in einem Überschuss an H₂.

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Volume123, Issue24

June 6, 2011

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A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides^†

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A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides†

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A Bifunctional Mechanism for Ethene Dimerization: Catalysis by Rhodium Complexes on Zeolite HY in the Absence of Halides^†