Angewandte Chemie
Volume 122, Issue 35 p. 6140
Innentitelbild

Innentitelbild: Reaction of Singlet Dioxygen with Phosphine–Borane Derivatives: From Transient Phosphine Peroxides to Crystalline Peroxoboronates (Angew. Chem. 35/2010)

Susana Porcel Dr., 

Susana Porcel Dr.

Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)

CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204

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Ghenwa Bouhadir Dr., 

Ghenwa Bouhadir Dr.

Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)

CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204

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Nathalie Saffon Dr., 

Nathalie Saffon Dr.

Structure Fédérative Toulousaine en Chimie Moléculaire, Toulouse (France)

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Laurent Maron Dr., 

Laurent Maron Dr.

Université de Toulouse, INSA, UPS, LPCNO, 135 avenue de Rangueil, 31077 Toulouse (France)

CNRS, LPCNO UMR 5215, 31077 Toulouse (France)

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Didier Bourissou Dr., 

Didier Bourissou Dr.

Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)

CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204

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First published: 12 August 2010
https://doi.org/10.1002/ange.201003227

Graphical Abstract

Ambiphile Phosphan-Boronate spalten Singulett-Disauerstoff unter milden Bedingungen. Wie D. Bourissou et al. in ihrer Zuschrift auf S. 6322 ff. erläutern, lagern sich dabei die zunächst gebildeten Phosphanperoxide spontan in stabile kristalline Peroxoboronate um. Bildgestaltung Christian Pradel.

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