Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)†
Gregorio Guisado-Barrios Dr.
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/
Search for more papers by this authorJean Bouffard Dr.
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/
Search for more papers by this authorBruno Donnadieu
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/
Search for more papers by this authorGuy Bertrand Prof.
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/
Search for more papers by this authorGregorio Guisado-Barrios Dr.
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/
Search for more papers by this authorJean Bouffard Dr.
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/
Search for more papers by this authorBruno Donnadieu
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/
Search for more papers by this authorGuy Bertrand Prof.
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403 (USA), Fax: (+1) 951-827-2725 http://research.chem.ucr.edu/groups/bertrand/guybertrandwebpage/
Search for more papers by this authorWe are grateful to the NIH (R01 GM 68825) and the DOE (DE-FG02-09ER16069) for financial support of this work.
Graphical Abstract
Mit einem Klick zu MICs: Eine kurze modulare Synthese führt zu neuartigen stabilen Heterocyclen mit einem freien Elektronenpaar an einem Kohlenstoffzentrum. Diese mesoionischen Verbindungen sind bessere Donoren als klassische N-heterocyclische Carbene, und sie sind durch Deprotonierung der konjugierten Säuren mit vergleichsweise milden Basen zugänglich.
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