Single-Crystal-to-Single-Crystal Transformations of Two Three-Dimensional Coordination Polymers through Regioselective [2+2] Photodimerization Reactions†
Dong Liu
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorZhi-Gang Ren Dr.
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorHong-Xi Li Dr.
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorJian-Ping Lang Prof. Dr.
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorNi-Ya Li
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorBrendan F. Abrahams Prof.
School of Chemistry, University of Melbourne, Victoria 3010 (Australia)
Search for more papers by this authorDong Liu
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorZhi-Gang Ren Dr.
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorHong-Xi Li Dr.
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorJian-Ping Lang Prof. Dr.
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorNi-Ya Li
College of Chemistry, Chemical Engineering and Materials Science, Suzhou University, 199 RenAi Road, Suzhou 215123, Jiangsu (P. R. China), Fax: (+86) 512-6588-0089
Search for more papers by this authorBrendan F. Abrahams Prof.
School of Chemistry, University of Melbourne, Victoria 3010 (Australia)
Search for more papers by this authorThis work was financially supported by the National Natural Science Foundation of China (Grant Nos. 20525101, 20871088 and 90922018), the Nature Science Key Basic Research of Jiangsu Province for Higher Education (09KJA150002), the State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry (2008-25), the Qin-Lan, and the “333” Projects of Jiangsu Province, and the “SooChow Scholar” Program and Program for Innovative Research Team of Suzhou University.
Graphical Abstract
Im Kristall: Einkristall-zu-Einkristall-Umwandlungen von zwei 3D-Koordinationspolymeren, {[Zn4(μ3-OH)2(5-sipa)2(1,4-bpeb)2]⋅4 H2O}n (siehe Bild; C hellblau, N dunkelblau, H grün) und dem Cadmium-Analogon, durch photochemische [2+2]-Cycloadditionen ergaben die entsprechenden verknüpften 3D-Koordinationspolymere.
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
| Filename | Description |
|---|---|
| ange_201001551_sm_miscellaneous_information.pdf1.5 MB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aK. Hanson, N. Calin, D. Bugaris, M. Scancella, S. C. Sevov, J. Am. Chem. Soc. 2004, 126, 10502;
- 1bT. K. Maji, K. Uemura, H. Chang, R. Matsuda, S. Kitagawa, Angew. Chem. 2004, 116, 3331; Angew. Chem. Int. Ed. 2004, 43, 3269;
- 1cY. J. Zhang, T. Liu, S. Kanegawa, O. Sato, J. Am. Chem. Soc. 2009, 131, 7942.
- 2
- 2aT. Kawamichi, T. Kodama, M. Kawano, M. Fujita, Angew. Chem. 2008, 120, 8150;
10.1002/ange.200802545 Google ScholarAngew. Chem. Int. Ed. 2008, 47, 8030;
- 2bT. Kawamichi, T. Haneda, M. Kawano, M. Fujita, Nature 2009, 461, 633.
- 3
- 3aZ. Q. Wang, S. M. Cohen, Angew. Chem. 2008, 120, 4777; Angew. Chem. Int. Ed. 2008, 47, 4699;
- 3bA. D. Burrows, C. G. Frost, M. F. Mahon, C. Richardson, Angew. Chem. 2008, 120, 8610;
10.1002/ange.200802908 Google ScholarAngew. Chem. Int. Ed. 2008, 47, 8482.
- 4
- 4aL. R. MacGillivray, G. S. Papaefstathiou, T. Friščić, T. D. Hamilton, D. K. Bučar, Q. L. Chu, D. B. Varshney, I. G. Georgiev, Acc. Chem. Res. 2008, 41, 280;
- 4bT. Friščić, L. R. MacGillivray, Z. Kristallogr. 2005, 220, 351;
- 4cA. E. Keating, M. A. Garcia-Garibay in Molecular and Supramolecular Photochemistry, Vol. 2 (Eds.: ), Marcel Dekker, New York, 1998, 195;
- 4dS. Y. Yang, P. Naumov, S. Fukuzumi, J. Am. Chem. Soc. 2009, 131, 7247.
- 5
- 5aG. S. Papaefstathiou, Z. M. Zhong, L. Geng, L. R. MacGillivray, J. Am. Chem. Soc. 2004, 126, 9158;
- 5bQ. L. Chu, D. C. Swenson, L. R. MacGillivray, Angew. Chem. 2005, 117, 3635; Angew. Chem. Int. Ed. 2005, 44, 3569;
- 5cY. F. Han, Y. J. Lin, W. G. Jia, G. L. Wang, G. X. Jin, Chem. Commun. 2008, 1807.
- 6
- 6aN. L. Toh, M. Nagarathinam, J. J. Vittal, Angew. Chem. 2005, 117, 2277; Angew. Chem. Int. Ed. 2005, 44, 2237;
- 6bJ. F. Eubank, V. C. Kravtsov, M. Eddaoudi, J. Am. Chem. Soc. 2007, 129, 5820;
- 6cM. H. Mir, L. L. Koh, G. K. Tan, J. J. Vittal, Angew. Chem. 2010, 122, 400;
10.1002/ange.200905898 Google ScholarAngew. Chem. Int. Ed. 2010, 49, 390.
- 7aI. G. Georgiev, L. R. MacGillivray, Chem. Soc. Rev. 2007, 36, 1239;
- 7bJ. J. Vittal, Coord. Chem. Rev. 2007, 251, 1781;
- 7cM. Nagarathinam, A. M. P. Peedikakkal, J. J. Vittal, Chem. Commun. 2008, 5277.
- 8aX. Y. Wang, Z. M. Wang, S. Gao, Chem. Commun. 2007, 1127;
- 8bW. L. Nie, G. Erker, G. Kehr, R. Fröhlich, Angew. Chem. 2004, 116, 313; Angew. Chem. Int. Ed. 2004, 43, 310;
- 8cJ. Paradies, I. Greger, G. Kehr, G. Erker, K. Bergander, R. Fröhlich, Angew. Chem. 2006, 118, 7792;
10.1002/ange.200601592 Google ScholarAngew. Chem. Int. Ed. 2006, 45, 7630;
- 8dD. Liu, H. X. Li, Z. G. Ren, Y. Chen, Y. Zhang, J. P. Lang, Cryst. Growth Des. 2009, 9, 4562.
- 9
- 9aG. S. Papaefstathiou, I. G. Georgiev, T. Friščić, L. R. MacGillivray, Chem. Commun. 2005, 3974;
- 9bM. Nagarathinam, J. J. Vittal, Angew. Chem. 2006, 118, 4443;
10.1002/ange.200600376 Google ScholarAngew. Chem. Int. Ed. 2006, 45, 4337;
- 9cM. Nagarathinam, J. J. Vittal, Chem. Commun. 2008, 438;
- 9dA. M. P. Peedikakkal, J. J. Vittal, Chem. Eur. J. 2008, 14, 5329.
- 10
- 10aL. R. MacGillivray, J. L. Reid, J. A. Ripmeester, J. Am. Chem. Soc. 2000, 122, 7817;
- 10bT. Friščić, L. R. MacGillivray, Chem. Commun. 2003, 1306;
- 10cT. Friščić, L. R. MacGillivray, Aust. J. Chem. 2006, 59, 613.
- 11J. R. Li, R. J. Kuppler, H. C. Zhou, Chem. Soc. Rev. 2009, 38, 1477.
- 12Crystal data for 1: triclinic, P
, a=9.4093(19), b=9.876(2), c=18.307(4) Å, α=79.35(3), β=87.30(3), γ=68.20(3)°, V=1551.9(7) Å3, Z=2, ρcalcd=1.522 g cm−3, μ=1.669 cm−1, R1=0.059, wR2=0.162, GOF=1.175. 2: triclinic, P
, a=9.5591(19), b=9.782(2), c=18.288(4) Å, α=78.75(3), β=86.28(3), γ=68.73(3)°, V=1562.9(7) Å3, Z=2, ρcalcd=1.469 g cm−3, μ=1.653 cm−1, R1=0.104, wR2=0.196, GOF=1.178. 3: monoclinic, P21/c, a=11.870(2), b=11.798(2), c=17.924(4) Å, β=95.03(3)°, V=2500.5(8) Å3, Z=4, ρcalcd=1.564 g cm−3, μ=0.913 cm−1, R1=0.039, wR2=0.084, GOF=1.087. 4: monoclinic, P21/c, a=11.804(2), b=11.912(2), c=18.226(4) Å, β=96.12(3)°, V=2548.1(8) Å3, Z=4, ρcalcd=1.535 g cm−3, μ=0.896 cm−1, R1=0.134, wR2=0.248, GOF=1.152. CCDC 761121, 761122, 761123, and 761124 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
- 13G. M. J. Schmidt, Pure Appl. Chem. 1971, 27, 647.
- 14G. S. Papaefstathiou, T. Friščić, L. R. MacGillivray, J. Am. Chem. Soc. 2005, 127, 14160.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
