Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel†
Job Boekhoven
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorAurelie M. Brizard Dr.
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorKrishna N. K. Kowlgi
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorGer J. M. Koper Dr.
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorRienk Eelkema Dr.
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorJan H. van Esch Prof. Dr.
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorJob Boekhoven
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorAurelie M. Brizard Dr.
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorKrishna N. K. Kowlgi
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorGer J. M. Koper Dr.
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorRienk Eelkema Dr.
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorJan H. van Esch Prof. Dr.
Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (The Netherlands), Fax: (+31) 15-278-4289 http://www.dct.tudelft.nl/sas
Search for more papers by this authorWe thank Marta E. Dobrowolska for obtaining SEM micrographs. We acknowledge financial support from the Netherlands Organization for Research (NWO).
Graphical Abstract
Die Natur macht's vor: Die dissipative Selbstorganisation eines synthetischen Gelbildners (blau, siehe Bild) wird durch ein Alkylierungsreagens angetrieben und führt über einen aktivierten Baustein (rot) als Zwischenstufe zur Bildung eines Fasernetzwerks. Nach vollständiger Ausschöpfung der Energieressourcen kehrt das System in das thermodynamische Gleichgewicht zurück.
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