Dynamics of Benzene Rings in MIL-53(Cr) and MIL-47(V) Frameworks Studied by 2H NMR Spectroscopy†
Daniil I. Kolokolov
Université Lyon 1, CNRS, UMR 5256, IRCELYON, Institut de Recherches sur la Catalyse et l'Environnement de LYON, 2. Av. A. Einstein, 69626 Villeurbanne (France)
Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090 (Russia)
Search for more papers by this authorHervé Jobic Dr.
Université Lyon 1, CNRS, UMR 5256, IRCELYON, Institut de Recherches sur la Catalyse et l'Environnement de LYON, 2. Av. A. Einstein, 69626 Villeurbanne (France)
Search for more papers by this authorAlexander G. Stepanov Dr.
Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090 (Russia)
Search for more papers by this authorVincent Guillerm
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)
Search for more papers by this authorThomas Devic Dr.
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)
Search for more papers by this authorChristian Serre Dr.
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)
Search for more papers by this authorGérard Férey Prof.
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)
Search for more papers by this authorDaniil I. Kolokolov
Université Lyon 1, CNRS, UMR 5256, IRCELYON, Institut de Recherches sur la Catalyse et l'Environnement de LYON, 2. Av. A. Einstein, 69626 Villeurbanne (France)
Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090 (Russia)
Search for more papers by this authorHervé Jobic Dr.
Université Lyon 1, CNRS, UMR 5256, IRCELYON, Institut de Recherches sur la Catalyse et l'Environnement de LYON, 2. Av. A. Einstein, 69626 Villeurbanne (France)
Search for more papers by this authorAlexander G. Stepanov Dr.
Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090 (Russia)
Search for more papers by this authorVincent Guillerm
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)
Search for more papers by this authorThomas Devic Dr.
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)
Search for more papers by this authorChristian Serre Dr.
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)
Search for more papers by this authorGérard Férey Prof.
Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 78035 Versailles Cedex (France)
Search for more papers by this authorThis work was performed in a frame of French-Russian Laboratory of Catalysis. The work was supported by the Russian Foundation for Basic Research (grants no. 05-03-34762, 09-03-93113), and the ANR (NoMAC project)
Graphical Abstract
Die Rotationsdynamiken von Benzolringen im flexiblen MIL-53- und im starren MIL-47-Gerüst wurden durch 2H-NMR-Spektroskopie untersucht. In beiden Fällen werden 180°-Flips beobachtet, wobei der Flip-Prozess in MIL-53 schneller ist. Zur Simulation der experimentellen Spektren (links) reicht die Berücksichtigung der quadrupolaren Wechselwirkung nicht aus (Mitte): Auch der paramagnetische Effekt muss einbezogen werden (rechts).
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