Palladium-Catalyzed Aerobic Oxidative Carbonylation of Arylboronate Esters under Mild Conditions†
Qiang Liu
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorGang Li
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorJun He
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorJing Liu Dr.
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorPeng Li
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorAiwen Lei Prof.
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, 730000 Lanzhou (China)
Search for more papers by this authorQiang Liu
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorGang Li
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorJun He
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorJing Liu Dr.
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorPeng Li
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
Search for more papers by this authorAiwen Lei Prof.
The College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei (China), Fax: (+86) 27-6875-4067 http://www.chem.whu.edu.cn/GCI_WebSite/main.htm
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, 730000 Lanzhou (China)
Search for more papers by this authorThis work was supported by the National Natural Science Foundation of China (20772093, 20972118, and 20832003), and the Doctoral Fund of the Ministry of Education of China (20060486005).
Graphical Abstract
Mit CO und Luft: Die Titelreaktion mit [PdCl2(PPh3)2] als Katalysatorvorstufe ergab unter sehr milden Bedingungen (leichter Überdruck von CO und Luft, 40→50 °C) zahlreiche Arylcarbonsäureester 2 in guten bis hervorragenden Ausbeuten. Bemerkenswert war die Selektivität für die oxidative Carbonylierung gegenüber der Homokupplung der Boronsäureester 1.
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