A Rare (3,4)-Connected Chalcogenide Superlattice and Its Photoelectric Effect†
Qichun Zhang
Department of Chemistry, University of California, Riverside, CA 92521, USA, Fax: (+1) 951-827-4713
Search for more papers by this authorYang Liu Dr.
Department of Chemistry, University of California, Riverside, CA 92521, USA, Fax: (+1) 951-827-4713
Search for more papers by this authorXianhui Bu Prof. Dr.
Department of Chemistry and Biochemistry, California State University, 1250 Bellflower Blvd, Long Beach, CA 90840, USA
Search for more papers by this authorTao Wu
Department of Chemistry, University of California, Riverside, CA 92521, USA, Fax: (+1) 951-827-4713
Search for more papers by this authorPingyun Feng Prof. Dr.
Department of Chemistry, University of California, Riverside, CA 92521, USA, Fax: (+1) 951-827-4713
Search for more papers by this authorQichun Zhang
Department of Chemistry, University of California, Riverside, CA 92521, USA, Fax: (+1) 951-827-4713
Search for more papers by this authorYang Liu Dr.
Department of Chemistry, University of California, Riverside, CA 92521, USA, Fax: (+1) 951-827-4713
Search for more papers by this authorXianhui Bu Prof. Dr.
Department of Chemistry and Biochemistry, California State University, 1250 Bellflower Blvd, Long Beach, CA 90840, USA
Search for more papers by this authorTao Wu
Department of Chemistry, University of California, Riverside, CA 92521, USA, Fax: (+1) 951-827-4713
Search for more papers by this authorPingyun Feng Prof. Dr.
Department of Chemistry, University of California, Riverside, CA 92521, USA, Fax: (+1) 951-827-4713
Search for more papers by this authorThe authors thank Dr. Zhenyu Zhang for help with SEM. This work is supported by NSF (P.F.), the National Institutes of Health (X.B. 2 S06 GM063119-05), and Research Corporation (X.B. CC6593). P.F. is a Camille Dreyfus Teacher-Scholar.
Graphical Abstract
Lichtschalter: Das gezeigte photoelektrische Chalkogenid (Cd grün, S gelb; Ar-Reste weggelassen) hat eine (3,4)-verknüpfte offene Gerüststruktur, die aus großen Cd-S-SAr-Clustern aufgebaut ist, und weist eine Borazit-Topologie auf. Es wurde strukturell und hinsichtlich seiner optischen Eigenschaften charakterisiert, und das Übergitter erzeugt reproduzierbar einen transienten Photostrom bei Anregung mit sichtbarem Licht (siehe Bild). SAr=3-Methylbenzolthiolat.
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