Efficient CuO-Nanoparticle-Catalyzed CS Cross-Coupling of Thiols with Iodobenzene†
Laxmidhar Rout
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India, Fax: (+91) 361-269-0762
Search for more papers by this authorTamal K. Sen
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India, Fax: (+91) 361-269-0762
Search for more papers by this authorTharmalingam Punniyamurthy Dr.
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India, Fax: (+91) 361-269-0762
Present Address: Chemistry Research Laboratory, University of Oxford, Oxford OX1 3TA, UK
Search for more papers by this authorLaxmidhar Rout
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India, Fax: (+91) 361-269-0762
Search for more papers by this authorTamal K. Sen
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India, Fax: (+91) 361-269-0762
Search for more papers by this authorTharmalingam Punniyamurthy Dr.
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India, Fax: (+91) 361-269-0762
Present Address: Chemistry Research Laboratory, University of Oxford, Oxford OX1 3TA, UK
Search for more papers by this authorThis research was supported by the Council of Scientific and Industrial Research, New Delhi (01(2002)/05/EMR-II) and the Department of Science and Technology, New Delhi (SR/S1/OC-09/2002).
Graphical Abstract
Attraktiv und preiswert: Leicht erhältliche CuO-Nanopartikel kosten nicht nur weniger als andere Katalysatoren für die C-S-Kreuzkupplung, sie sind überdies schon bei moderaten Temperaturen und geringen Konzentrationen aktiv. Die Titelreaktion führt mit zahlreichen Alkyl- und Arylthiolen in hohen Ausbeuten zu den entsprechenden Sulfiden (siehe Schema).
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