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Magnesium Borohydride: Synthesis and Crystal Structure^†

Radovan Černý Dr.

[email protected]

Laboratoire de Cristallographie, Université de Genève, 24 Quai Ernest Ansermet, 1211 Genève 4, Switzerland, Fax: (+41) 223-796-108

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Yaroslav Filinchuk Dr.,

Yaroslav Filinchuk Dr.

[email protected]

Laboratoire de Cristallographie, Université de Genève, 24 Quai Ernest Ansermet, 1211 Genève 4, Switzerland, Fax: (+41) 223-796-108

Swiss–Norwegian Beam Lines at ESRF, BP-220, 38043 Grenoble, France, Fax: (+33) 476-88-2694

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Hans Hagemann Dr.,

Hans Hagemann Dr.

Département de Chimie Physique, Université de Genève, 30 Quai Ernest Ansermet, 1211 Genève 4, Switzerland

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Klaus Yvon Prof. Dr.,

Klaus Yvon Prof. Dr.

Laboratoire de Cristallographie, Université de Genève, 24 Quai Ernest Ansermet, 1211 Genève 4, Switzerland, Fax: (+41) 223-796-108

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Radovan Černý Dr.,

Radovan Černý Dr.

[email protected]

Laboratoire de Cristallographie, Université de Genève, 24 Quai Ernest Ansermet, 1211 Genève 4, Switzerland, Fax: (+41) 223-796-108

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Yaroslav Filinchuk Dr.,

Yaroslav Filinchuk Dr.

[email protected]

Laboratoire de Cristallographie, Université de Genève, 24 Quai Ernest Ansermet, 1211 Genève 4, Switzerland, Fax: (+41) 223-796-108

Swiss–Norwegian Beam Lines at ESRF, BP-220, 38043 Grenoble, France, Fax: (+33) 476-88-2694

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Hans Hagemann Dr.,

Hans Hagemann Dr.

Département de Chimie Physique, Université de Genève, 30 Quai Ernest Ansermet, 1211 Genève 4, Switzerland

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Klaus Yvon Prof. Dr.,

Klaus Yvon Prof. Dr.

Laboratoire de Cristallographie, Université de Genève, 24 Quai Ernest Ansermet, 1211 Genève 4, Switzerland, Fax: (+41) 223-796-108

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First published: 13 July 2007

https://doi.org/10.1002/ange.200700773

Citations: 40

^†

The authors thank N. Amstutz for help with the synthesis. The assistance of W. van Beek with the synchrotron data collection and the help of D. Sheptyakov with the neutron data collection are highly appreciated. The synchrotron data used for the indexing were measured by G. Renaudin. This work was supported by the Swiss National Science Foundation and the Swiss Federal Office of Energy.

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Graphical Abstract

Unerwartet komplexe Strukturen: Die strukturelle Charakterisierung von gut kristallisiertem Mg(BH₄)₂-Pulver anhand von Synchrotron-Röntgenbeugungs- und Neutronenbeugungsdaten enthüllte, dass Mg(BH₄)₂ ein neuartiges und bemerkenswert komplexes dreidimensionales Gerüst bildet, in dem jedes Mg²⁺-Ion (blau) tetraedrisch von vier [BH₄]⁻-Ionen umgeben ist (B rot, H grau; siehe Bild).

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References

1F. Schüth, B. Bogdanovic, M. Felderhoff, Chem. Commun. 2004, 2249–2258.
10.1039/B406522K
CAS PubMed Web of Science® Google Scholar
2E. Wiberg, R. Bauer, Z. Naturforsch. B 1950, 5, 397.
Web of Science® Google Scholar
3A. M. F. R. Pinto, D. S. Falcão, R. A. Silva, C. M. Rangel, Int. J. Hydrogen Energy 2006, 31, 1341–1347.
10.1016/j.ijhydene.2005.11.015
CAS Web of Science® Google Scholar
4M. Bremer, H. Nöth, M. Warchhold, Eur. J. Inorg. Chem. 2003, 111–119; and references therein.
10.1002/ejic.200390011
CAS Web of Science® Google Scholar
5V. N. Konoplev, Russ. J. Inorg. Chem. 1980, 25, 964–966; and references therein.
Google Scholar
6H. D. Batha, E. D. Whitney, T. L. Heying, J. P. Faust, S. Papeti, J. Appl. Chem. 1962, 12, 478–481; and references therein.
10.1002/jctb.5010121102
CAS Google Scholar
7V. N. Konoplev, V. M. Bakulina, Russ. Chem. Bull. 1971, 20, 136–138.
10.1007/BF00849335
Google Scholar
8P. Vajeeston, P. Ravindran, A. Kjekshus, H. Fjellvåg, Appl. Phys. Lett. 2006, 89, 071906.
10.1063/1.2217159
CAS Web of Science® Google Scholar
9Y. Nakamori, K. Miwa, A. Ninomiya, H. Li, N. Ohba, S. Towata, A. Züttel, S. Orimo, Phys. Rev. B 2006, 74, 045126.
10.1103/PhysRevB.74.045126
CAS Web of Science® Google Scholar
10K. Yvon, B. Bertheville, J. Alloys Compd. 2006, 425, 101–108.
10.1016/j.jallcom.2006.01.049
CAS Web of Science® Google Scholar
11J.-P. Soulié, G. Renaudin, R. Černý, K. Yvon, J. Alloys Compd. 2002, 346, 200–205.
10.1016/S0925-8388(02)00521-2
CAS Web of Science® Google Scholar
12D. S. Marynick, W. N. Lipscomb, Inorg. Chem. 1972, 11, 820–823.
10.1021/ic50110a033
CAS Web of Science® Google Scholar
13K. Miwa, M. Aoki, T. Noritake, N. Ohba, Y. Nakamori, S. Towata, A. Züttel, S. Orimo, Phys. Rev. B 2006, 74, 155122.
10.1103/PhysRevB.74.155122
CAS Web of Science® Google Scholar
14P. H. Bird, M. R. Churchill, Chem. Commun. (London) 1967, 403.
10.1039/c19670000403
CAS Web of Science® Google Scholar
15S. Gomes, H. Hagemann, K. Yvon, J. Alloys Compd. 2002, 346, 206–210.
10.1016/S0925-8388(02)00668-0
CAS Web of Science® Google Scholar
16P. Carbonnière, H. Hagemann, J. Phys. Chem. A 2006, 110, 9927–9933.
10.1021/jp062091d
CAS PubMed Web of Science® Google Scholar
17G. Renaudin, S. Gomes, H. Hagemann, L. Keller, K. Yvon, J. Alloys Compd. 2004, 375, 98–106.
10.1016/j.jallcom.2003.11.018
CAS Web of Science® Google Scholar
18K. Miwa, N. Ohba, S. Towata, Y. Nakamori, S. Orimo, Phys. Rev. B 2004, 69, 245120.
10.1103/PhysRevB.69.245120
CAS Web of Science® Google Scholar
19J. W. Nibler, D. F. Shriver, T. H. Cook, J. Chem. Phys. 1971, 54, 5257–5266.
10.1063/1.1674823
CAS Web of Science® Google Scholar
20B. E. Smith, B. D. James, R. M. Peachey, Inorg. Chem. 1977, 16, 2057–2062.
10.1021/ic50174a048
CAS Web of Science® Google Scholar
21H. I. Schlesinger, H. C. Brown, E. K. Hyde, J. Am. Chem. Soc. 1953, 75, 209–213.
10.1021/ja01097a055
CAS Web of Science® Google Scholar
22H. C. Brown, Y. M. Choi, S. Narasimham, Inorg. Chem. 1982, 21, 3657–3661.
10.1021/ic00140a014
CAS Web of Science® Google Scholar
23V. Favre-Nicolin, R. Černý, J. Appl. Crystallogr. 2002, 35, 734–743.
10.1107/S0021889802015236
CAS Web of Science® Google Scholar
24A. A. Coelho, TOPAS-Academic, http://members.optusnet.com.au/alancoelho, 2004.
Google Scholar

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Volume119, Issue30

July 23, 2007

Pages 5867-5869

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Magnesium Borohydride: Synthesis and Crystal Structure^†

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Magnesium Borohydride: Synthesis and Crystal Structure^†