Volume 117, Issue 42 pp. 7031-7034
Zuschrift

Aqueous FeIVO: Spectroscopic Identification and Oxo-Group Exchange

Oleg Pestovsky Dr.

Oleg Pestovsky Dr.

Ames Laboratory, Iowa State University, Ames, IA 50011, USA, Fax: (+1) 515-294-5233

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Sebastian Stoian

Sebastian Stoian

Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061

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Emile L. Bominaar Prof. Dr.

Emile L. Bominaar Prof. Dr.

Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061

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Xiaopeng Shan Dr.

Xiaopeng Shan Dr.

Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029

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Eckard Münck Prof. Dr.

Eckard Münck Prof. Dr.

Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061

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Lawrence Que Jr. Prof. Dr.

Lawrence Que Jr. Prof. Dr.

Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029

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Andreja Bakac Prof. Dr.

Andreja Bakac Prof. Dr.

Ames Laboratory, Iowa State University, Ames, IA 50011, USA, Fax: (+1) 515-294-5233

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First published: 25 October 2005
Citations: 60

Supported under DOE Contract No. W-7405-ENG-82 (A.B.) and NIH grants EB001475 (E.M.) and GM-38767 (L.Q.)

Graphical Abstract

Eine Kombination von Techniken (Mößbauer- und Röntgenabsorptionsspektroskopie, H218O-Austauschexperimente und DFT-Rechnungen) ergab, dass bei der Reaktion von [Fe(H2O)6]2+ mit Ozon [(H2O)5FeIVO]2+ gebildet wird (siehe die berechnete Struktur). Die Oxidation ausgewählter Substrate mit [(H2O)5FeIVO]2+ lieferte Produkte, die sich von denen unterscheiden, die bei der Fenton-Reaktion oder bei Umsetzungen mit HO.-Radikalen entstehen.

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