Aqueous FeIVO: Spectroscopic Identification and Oxo-Group Exchange†
Correction(s) for this article
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Aqueous FeIVO: Spectroscopic Identification and Oxo-Group Exchange
- Oleg Pestovsky Dr.,
- Sebastian Stoian,
- Emile L. Bominaar Prof. Dr.,
- Xiaopeng Shan Dr.,
- Eckard Münck Prof. Dr.,
- Lawrence Que Prof. Dr.,
- Andreja Bakac Prof. Dr.,
- Volume 118Issue 3Angewandte Chemie
- pages: 348-348
- First Published online: January 5, 2006
Oleg Pestovsky Dr.
Ames Laboratory, Iowa State University, Ames, IA 50011, USA, Fax: (+1) 515-294-5233
Search for more papers by this authorSebastian Stoian
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061
Search for more papers by this authorEmile L. Bominaar Prof. Dr.
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061
Search for more papers by this authorXiaopeng Shan Dr.
Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorEckard Münck Prof. Dr.
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061
Search for more papers by this authorLawrence Que Jr. Prof. Dr.
Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorAndreja Bakac Prof. Dr.
Ames Laboratory, Iowa State University, Ames, IA 50011, USA, Fax: (+1) 515-294-5233
Search for more papers by this authorOleg Pestovsky Dr.
Ames Laboratory, Iowa State University, Ames, IA 50011, USA, Fax: (+1) 515-294-5233
Search for more papers by this authorSebastian Stoian
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061
Search for more papers by this authorEmile L. Bominaar Prof. Dr.
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061
Search for more papers by this authorXiaopeng Shan Dr.
Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorEckard Münck Prof. Dr.
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 12513, USA, Fax: (+1) 412-268-1061
Search for more papers by this authorLawrence Que Jr. Prof. Dr.
Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN 55455, USA, Fax: (+1) 612-624-7029
Search for more papers by this authorAndreja Bakac Prof. Dr.
Ames Laboratory, Iowa State University, Ames, IA 50011, USA, Fax: (+1) 515-294-5233
Search for more papers by this authorSupported under DOE Contract No. W-7405-ENG-82 (A.B.) and NIH grants EB001475 (E.M.) and GM-38767 (L.Q.)
Graphical Abstract
Eine Kombination von Techniken (Mößbauer- und Röntgenabsorptionsspektroskopie, H218O-Austauschexperimente und DFT-Rechnungen) ergab, dass bei der Reaktion von [Fe(H2O)6]2+ mit Ozon [(H2O)5FeIVO]2+ gebildet wird (siehe die berechnete Struktur). Die Oxidation ausgewählter Substrate mit [(H2O)5FeIVO]2+ lieferte Produkte, die sich von denen unterscheiden, die bei der Fenton-Reaktion oder bei Umsetzungen mit HO.-Radikalen entstehen.
Supporting Information
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