Volume 117, Issue 42 pp. 7062-7065
Zuschrift

Molecular and Polymeric Hybrids Based on Covalently Linked Polyoxometalates and Transition-Metal Complexes

Jeonghee Kang

Jeonghee Kang

Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USA, Fax: (+1) 816-235-5502

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Bubin Xu Dr.

Bubin Xu Dr.

Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USA, Fax: (+1) 816-235-5502

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Zhonghua Peng Prof.

Zhonghua Peng Prof.

Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USA, Fax: (+1) 816-235-5502

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Xiaodong Zhu Dr.

Xiaodong Zhu Dr.

Department of Chemistry, University of Missouri-Kansas City, Kansas City, MO 64110, USA, Fax: (+1) 816-235-5502

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Yongge Wei Dr.

Yongge Wei Dr.

Department of Chemistry, Tsinghua University, Beijing, 100080, China

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Douglas R. Powell Dr.

Douglas R. Powell Dr.

Department of Chemistry, University of Kansas, Lawrence, KS 66045, USA

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First published: 25 October 2005
Citations: 17

This work is supported by National Science Foundation (DMR 0134032) and the Office of Naval Research. We thank Dr. Nathan D. Leigh for the ESI-MS measurements on hybrid 5.

Graphical Abstract

Ein rationaler Ansatz wurde zum Aufbau von Hybridverbindungen aus metallorganischen Komplexen und Polyoxometallaten (POMs) entwickelt. Die POM-Cluster sind mit den Komplexeinheiten über π-konjugierte Brücken verknüpft. Die Synthesestrategie – Funktionalisierung der POMs mit iodierten Gruppen, Verankerung des Terpyridin-Liganden, Koordination des Metalls – ist im Schema gezeigt.

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