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Chiral Phosphine–Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Boronic Acids to Maleimides^†

Ryo Shintani Dr.

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

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Wei-Liang Duan,

Wei-Liang Duan

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

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Takashi Nagano Dr.,

Takashi Nagano Dr.

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

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Atsushi Okada,

Atsushi Okada

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

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Tamio Hayashi Prof. Dr.,

Tamio Hayashi Prof. Dr.

[email protected]

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

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Ryo Shintani Dr.,

Ryo Shintani Dr.

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

Search for more papers by this author

Wei-Liang Duan,

Wei-Liang Duan

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

Search for more papers by this author

Takashi Nagano Dr.,

Takashi Nagano Dr.

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

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Atsushi Okada,

Atsushi Okada

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

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Tamio Hayashi Prof. Dr.,

Tamio Hayashi Prof. Dr.

[email protected]

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988

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First published: 08 July 2005

https://doi.org/10.1002/ange.200501305

Citations: 73

^†

Support was provided in part by a Grant-in-Aid for Scientific Research, the Ministry of Education, Culture, Sports, Science, and Technology, Japan (21 COE on Kyoto University Alliance for Chemistry).

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Graphical Abstract

Doppelt hält besser: Die neuartigen chiralen Phosphin-Olefin-Liganden 1 a und 1 b koordinieren im zweizähnigen Bindungsmodus an einige Übergangsmetalle. Die Liganden waren effektiv in der hoch enantioselektiven Rhodium-katalysierten 1,4-Addition von Arylboronsäuren an Maleimide (siehe Schema).

Supporting Information

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Volume117, Issue29

July 18, 2005

Pages 4687-4690

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Chiral Phosphine–Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Boronic Acids to Maleimides^†

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Chiral Phosphine–Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Boronic Acids to Maleimides†

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Supporting Information

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Chiral Phosphine–Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl Boronic Acids to Maleimides^†