Asymmetrische allylische Substitution mit chiralen Kupferkomplexen als Katalysatoren
Hideki Yorimitsu Dr.
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2438
Search for more papers by this authorKoichiro Oshima Prof. Dr.
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2438
Search for more papers by this authorHideki Yorimitsu Dr.
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2438
Search for more papers by this authorKoichiro Oshima Prof. Dr.
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan, Fax: (+81) 75-383-2438
Search for more papers by this authorGraphical Abstract
Kupfer ergänzt Palladium als Katalysator bei der asymmetrischen allylischen Substitution (siehe Schema). Die Katalyse mit Palladium erfordert weiche Nucleophile, um hohe Stereo- und Regioselektivität zu erzielen. Harte Nucleophile wie Grignard- und Organozinkreagentien können dagegen bei der Katalyse mit Kupfer eingesetzt werden. Die aktuellen Fortschritte lassen eine vielversprechende Zukunft der Kupfer-Katalyse erwarten.
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