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Understanding the Window Effect in Zeolite Catalysis^†

David Dubbeldam Dr.

[email protected]

Department of Chemical Engineering, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands, Fax: (+31) 20-525-5604

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Sofía Calero,

Sofía Calero

Department of Chemical Engineering, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands, Fax: (+31) 20-525-5604

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Theo L. M. Maesen,

Theo L. M. Maesen

Chevron Texaco, Energy Research and Technology Company, Chevron Way 100, Richmond CA 94802-0627, USA

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Berend Smit,

Berend Smit

Department of Chemical Engineering, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands, Fax: (+31) 20-525-5604

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David Dubbeldam Dr.,

David Dubbeldam Dr.

[email protected]

Department of Chemical Engineering, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands, Fax: (+31) 20-525-5604

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Sofía Calero,

Sofía Calero

Department of Chemical Engineering, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands, Fax: (+31) 20-525-5604

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Theo L. M. Maesen,

Theo L. M. Maesen

Chevron Texaco, Energy Research and Technology Company, Chevron Way 100, Richmond CA 94802-0627, USA

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Berend Smit,

Berend Smit

Department of Chemical Engineering, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands, Fax: (+31) 20-525-5604

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First published: 07 August 2003

https://doi.org/10.1002/ange.200351110

Citations: 4

^†

We would like to thank the Netherlands Research Council for Chemical Sciences (CW), the European Commission for a Marie Curie Fellowship to S.C., ChevronTexaco for financial support, and C. Wilson, C. H. Roemkens, A. Kuperman, S. I. Zones, and R. Krishna for their comments on our manuscript.

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Graphical Abstract

Entgegen der traditionellen Auffassung, dass Crack-Reaktionen in Zeolithen mit vollständiger Substratadsorption verlaufen, deuten Rechnungen für ERI-, AFX-, CHA-, RHO- und KFI-Zeolithe auf geringe Adsorption von Substraten hin, die eine ähnliche Größe wie die Zeolithhohlräume haben. Sehr lange Moleküle werden in oberflächennahen Poren teilweise adsorbiert. Der nichtadsorbierte Teil kann abgespalten und in ein Produkt eingebaut oder erneut adsorbiert werden. Dieser Mechanismus ist charakteristisch für Zeolith-Käfige mit Fenstern, deren Größe etwa dem Adsorbatdurchmesser entspricht.

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Volume115, Issue31

August 11, 2003

Pages 3752-3754

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Understanding the Window Effect in Zeolite Catalysis^†