Volume 115, Issue 24 pp. 2884-2888

Zuschrift

Selective Preparation of the [3,5-tBu₂-1,2,4-C₂P₃]⁻ Ion and Synthesis and Structure of the Cationic Species nido-[3,5-tBu₂-1,2,4-C₂P₃]⁺, Isoelectronic with [C₅R₅]⁺^†

Jason M. Lynam Dr.,

Jason M. Lynam Dr.

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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May C. Copsey,

May C. Copsey

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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Michael Green Prof.,

Michael Green Prof.

[email protected]

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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John C. Jeffery Dr.,

John C. Jeffery Dr.

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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John E. McGrady Dr.,

John E. McGrady Dr.

Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK

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Christopher A. Russell Dr.,

Christopher A. Russell Dr.

[email protected]

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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John M. Slattery,

John M. Slattery

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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Anthony C. Swain Dr.,

Anthony C. Swain Dr.

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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Jason M. Lynam Dr.,

Jason M. Lynam Dr.

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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May C. Copsey,

May C. Copsey

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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Michael Green Prof.,

Michael Green Prof.

[email protected]

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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John C. Jeffery Dr.,

John C. Jeffery Dr.

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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John E. McGrady Dr.,

John E. McGrady Dr.

Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK

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Christopher A. Russell Dr.,

Christopher A. Russell Dr.

[email protected]

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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John M. Slattery,

John M. Slattery

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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Anthony C. Swain Dr.,

Anthony C. Swain Dr.

School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK, Fax: (+44) 117-929-0509

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First published: 17 June 2003

https://doi.org/10.1002/ange.200351096

Citations: 24

^†

We thank the Leverhulme Trust (Emeritus Research Fellowship for M.G.), the Royal Society (University Research Fellowship for C.A.R.), the Ramsay Memorial Fellowship Trust (Research Fellowship for J.M.L.), the University of Bristol (M.G., C.A.R., J.M.L.), and the EPSRC (A.C.S., M.C.C., J.M.S.) for financial support. We would also like to thank Dr. Simon Duckett (York) for helpful discussions concerning the interpretation of NMR spectra.

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Graphical Abstract

Der kationische pyramidale P-C-Cluster 2 kann ausgehend von 1 (siehe Schema; •=CtBu) leicht erhalten werden. 1 ist außerdem eine ausgezeichnete Ausgangsverbindung für die Synthese des Anions 3. Dass das globale Energieminimum von [CH]₅⁺-Ionen nach Einbau von drei Phosphoratomen ( equation image CH) nicht mehr ein ungesättigter Cyclus, sondern eine gesättigte Käfigstruktur wie in 2 ist, wird durch DFT-Rechnungen bestätigt.

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Volume115, Issue24

June 23, 2003

Pages 2884-2888

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Selective Preparation of the [3,5-tBu₂-1,2,4-C₂P₃]⁻ Ion and Synthesis and Structure of the Cationic Species nido-[3,5-tBu₂-1,2,4-C₂P₃]⁺, Isoelectronic with [C₅R₅]⁺^†

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Selective Preparation of the [3,5-tBu2-1,2,4-C2P3]− Ion and Synthesis and Structure of the Cationic Species nido-[3,5-tBu2-1,2,4-C2P3]+, Isoelectronic with [C5R5]+†

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Selective Preparation of the [3,5-tBu₂-1,2,4-C₂P₃]⁻ Ion and Synthesis and Structure of the Cationic Species nido-[3,5-tBu₂-1,2,4-C₂P₃]⁺, Isoelectronic with [C₅R₅]⁺^†