Zuschrift
Organic-Based Layered Perovskites of Mixed-Valent Gold(I)/Gold(III) Iodides†
Laura M. Castro-Castro,
Arnold M. Guloy Prof.,
Laura M. Castro-Castro
Department of Chemistry, University of Houston, Houston, Texas, 77204–5641, USA, Fax: (+1) 713-743–2787
Search for more papers by this authorArnold M. Guloy Prof.
Department of Chemistry, University of Houston, Houston, Texas, 77204–5641, USA, Fax: (+1) 713-743–2787
Search for more papers by this authorLaura M. Castro-Castro,
Arnold M. Guloy Prof.,
Laura M. Castro-Castro
Department of Chemistry, University of Houston, Houston, Texas, 77204–5641, USA, Fax: (+1) 713-743–2787
Search for more papers by this authorArnold M. Guloy Prof.
Department of Chemistry, University of Houston, Houston, Texas, 77204–5641, USA, Fax: (+1) 713-743–2787
Search for more papers by this author†
This work was supported by the R.A. Welch Foundation, the Texas Center for Superconductivity at UH, and the National Science Foundation (CAREER Award, DMR-9733587). The authors are also grateful to Prof. P. S. Halasyamani for the TGA measurements.
Graphical Abstract
Blattgold: In neuartigen gemischtvalenten AuI/AuIII-Perowskitstrukturen werden Schichten aus [AuI2]−- und [AuI4]−-Einheiten durch I3−-Ionen und geeignete organische Dikationen zu dreidimensionalen Architekturen verbunden. Die experimentell bestimmten optischen Bandlücken dieser organisch-anorganischen Hybridhalbleiter sind kleiner als in Cs2Au2I6.
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