Solid-State Supramolecular Chirogenesis: High Optical Activity and Gradual Development of Zinc Octaethylporphyrin Aggregates
Victor V. Borovkov Dr.
Entropy Control Project, ICORP, JST, 4-6-3 Kamishinden, Toyonaka-shi, Osaka 560-0085, Japan, Fax: (+81) 6-6836-1636
Search for more papers by this authorTakunori Harada Dr.
Kuroda Chiromorphology Project, ERATO, JST, Park bldg., 4-7-6 Komaba, Meguro-ku, Tokyo 153-0041, Japan, Fax: (+81) 3-5452-0599
Search for more papers by this authorGuy A. Hembury Dr.
Entropy Control Project, ICORP, JST, 4-6-3 Kamishinden, Toyonaka-shi, Osaka 560-0085, Japan, Fax: (+81) 6-6836-1636
Search for more papers by this authorYoshihisa Inoue Prof. Dr.
Entropy Control Project, ICORP, JST, 4-6-3 Kamishinden, Toyonaka-shi, Osaka 560-0085, Japan, Fax: (+81) 6-6836-1636
Search for more papers by this authorReiko Kuroda Prof. Dr.
Kuroda Chiromorphology Project, ERATO, JST, Park bldg., 4-7-6 Komaba, Meguro-ku, Tokyo 153-0041, Japan, Fax: (+81) 3-5452-0599
Search for more papers by this authorVictor V. Borovkov Dr.
Entropy Control Project, ICORP, JST, 4-6-3 Kamishinden, Toyonaka-shi, Osaka 560-0085, Japan, Fax: (+81) 6-6836-1636
Search for more papers by this authorTakunori Harada Dr.
Kuroda Chiromorphology Project, ERATO, JST, Park bldg., 4-7-6 Komaba, Meguro-ku, Tokyo 153-0041, Japan, Fax: (+81) 3-5452-0599
Search for more papers by this authorGuy A. Hembury Dr.
Entropy Control Project, ICORP, JST, 4-6-3 Kamishinden, Toyonaka-shi, Osaka 560-0085, Japan, Fax: (+81) 6-6836-1636
Search for more papers by this authorYoshihisa Inoue Prof. Dr.
Entropy Control Project, ICORP, JST, 4-6-3 Kamishinden, Toyonaka-shi, Osaka 560-0085, Japan, Fax: (+81) 6-6836-1636
Search for more papers by this authorReiko Kuroda Prof. Dr.
Kuroda Chiromorphology Project, ERATO, JST, Park bldg., 4-7-6 Komaba, Meguro-ku, Tokyo 153-0041, Japan, Fax: (+81) 3-5452-0599
Search for more papers by this authorGraphical Abstract
Die langsame Bildung helicaler J-Aggregate erfolgt bei der Wechselwirkung von (achiralem) Zinkoctaethylporphyrin mit enantiomerenreinem 1-Cyclohexylethylamin im festen Zustand. Diese stabilen chiralen Festkörperaggregate zeigen ausgeprägte optische Aktivität, wie die Circulardichroismus-Spektren erkennen lassen (siehe Bild).
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