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Hinweise auf ein Gleichgewicht zwischen μ-Alkin-und Alkylidin-Komplexen von Wolframalkoxiden: [W₂(OR)₆(μ-C₂R′₂)] ⇋ 2[(RO)₃WCR′]^†

Corresponding Author

Prof. Dr. Malcolm H Chisholm

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)Search for more papers by this author

Brian K. Conroy,

Brian K. Conroy

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)

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John C. Huffman,

John C. Huffman

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)

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Nancy S. Marchant,

Nancy S. Marchant

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)

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Prof. Dr. Malcolm H Chisholm,

Corresponding Author

Prof. Dr. Malcolm H Chisholm

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)Search for more papers by this author

Brian K. Conroy,

Brian K. Conroy

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)

Search for more papers by this author

John C. Huffman,

John C. Huffman

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)

Search for more papers by this author

Nancy S. Marchant,

Nancy S. Marchant

Department of Chemistry and Molecular Structure Center Indiana University, Bloomington, IN 47405 (USA)

Search for more papers by this author

First published: Mai 1986

https://doi.org/10.1002/ange.19860980512

Citations: 7

^†

Diese Arbeit wurde vom US Department of Energy, Office of Basic Sciences, Chemical Division, und vom Wrubel Computing Center gefördert.

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Abstract

Die Spaltung von Alkinen in der Koordinationssphäre von Metallen liegt einer neuen Synthese von Alkylidin-überdachten W₃-Komplexen zugrunde. Bei der Umsetzung von Alkinen R′CCR′ mit [W₂(OCH₂tBu)₆(py)₂] im Molverhältnis 1:3 entstehen die Komplexe [W₃(μ₃-CR′)(OCH₂tBu)₉]; die Bildungsgeschwindigkeit dieser Komplexe hängt von R′ ab (Et≈Ph>Me) – ein Hinweis auf das im Titel formulierte Gleichgewicht.

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Volume98, Issue5

Mai 1986

Pages 448-449

This is the

German version

of Angewandte Chemie.

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Hinweise auf ein Gleichgewicht zwischen μ-Alkin-und Alkylidin-Komplexen von Wolframalkoxiden: [W₂(OR)₆(μ-C₂R′₂)] ⇋ 2[(RO)₃WCR′]^†

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Hinweise auf ein Gleichgewicht zwischen μ-Alkin-und Alkylidin-Komplexen von Wolframalkoxiden: [W2(OR)6(μ-C2R′2)] ⇋ 2[(RO)3WCR′]†

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Hinweise auf ein Gleichgewicht zwischen μ-Alkin-und Alkylidin-Komplexen von Wolframalkoxiden: [W₂(OR)₆(μ-C₂R′₂)] ⇋ 2[(RO)₃WCR′]^†