Die Halogenomolybdate(1) und (2) sind die ersten ihrer Art. Während Verbindungen mit dem analogen Anion CrO3X− seit langem bekannt sind, scheiterte die Bildung von MoO3X− bisher daran, daß Mo die Koordinationszahl 6 bevorzugt. Ein ausreichend großes Kation vermag dies jedoch zu ändern.
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