Chapter 34

Origin and Evolution of Non-Metallic Inclusions For Al-Killed Steel During Eaf-Lf-Vd-Cc Process

Tang Hai-yan

Tang Hai-yan

State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing; No.30 Xueyuan Road; Beijing, China

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing; No.30 Xueyuan Road; Beijing, China

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Guo Xiao-chen

Guo Xiao-chen

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing; No.30 Xueyuan Road; Beijing, China

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Cheng Peng-fei

Cheng Peng-fei

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing; No.30 Xueyuan Road; Beijing, China

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Liang Yong-cang

Liang Yong-cang

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing; No.30 Xueyuan Road; Beijing, China

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Li Jing-she

Li Jing-she

School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing; No.30 Xueyuan Road; Beijing, China

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Zhao Baojun

Zhao Baojun

School of Chemical Engineering, The University of Queensland, Brisbane, Australia

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First published: 03 February 2016

Summary

The origin and evolution of non-metallic inclusions for Al-killed casing steel during EAF-LF-VD-CC process were studied by industrial tracer experiments. The formations of Al2O3 and MgO·Al2O3 micro- and macro-inclusions from ladle slag were analyzed by theoretical calculations. The results show that micro-inclusions were formed during deoxidation and temperature decreasing in the process of casting, most of the macro-inclusions come from entrapped ladle and mold slags. In addition, most of the Al2O3 formed were modified into 12CaO·7Al2O3 and 3CaO·Al2O3 inclusions which are liquid at steelmaking temperature. MnS cannot be fully modified to CaS and it was only wrapped outside the alumina or calcium aluminate in the form of (Ca,Mn)S with the amount of Ca-Si wire fed during the test.

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