Heat Losses to Furnace Coolers as a Function of Process Intensity
M.W. Kennedy
Department of Materials Science and Engineering, Norwegian University of Science and Technology, Trondheim, Norway
ProVal Partners, SA, Avenue de Sévelin 6 b, Lausanne, Switzerland
Search for more papers by this authorA. MacRae
MacRae Technologies, Inc., 1000 Silver Maple Lane, Hayward, CA, USA
Search for more papers by this authorH. Haaland
4Elkem Technology, Drammensveien 169-171, Oslo, Norway
Search for more papers by this authorM.W. Kennedy
Department of Materials Science and Engineering, Norwegian University of Science and Technology, Trondheim, Norway
ProVal Partners, SA, Avenue de Sévelin 6 b, Lausanne, Switzerland
Search for more papers by this authorA. MacRae
MacRae Technologies, Inc., 1000 Silver Maple Lane, Hayward, CA, USA
Search for more papers by this authorH. Haaland
4Elkem Technology, Drammensveien 169-171, Oslo, Norway
Search for more papers by this authorJiann-Yang Hwang
Search for more papers by this authorP. Chris Pistorius
Search for more papers by this authorGerardo R.F. Alvear F.
Search for more papers by this authorOnuralp Yücel
Search for more papers by this authorLiyuan Cai
Search for more papers by this authorBaojun Zhao
Search for more papers by this authorDean Gregurek
Search for more papers by this authorVaradarajan Seshadri
Search for more papers by this authorSummary
Furnace refractories are in most cases chemically incompatible with smelter slag, which leads to a steady erosion in their thickness over time. Once too thin, refractory walls become mechanically unstable and catastrophic failure can result. Historically, external shell cooling was applied to generate a freeze lining of slag and thus prevent refractory erosion. Many modern high intensity smelting furnaces instead maintain their physical integrity by the use of internally cooled wall panels, plates or finger coolers. An initial refractory lining is often installed inside of the coolers, such that the furnace originally operates with a temperature (insulated) rather than a heat flux (freeze lined) boundary condition. This paper examines the change in slag-wall heat transfer coefficient and slag superheat as a function of process intensity. The implications of the changes in heat transfer on residual brick thickness are explored using analytical modelling.
References
- J. Kunze and R. Degel, "New Trends in Submerged Arc Furnace Technology," in Proceedings: Tenth International Ferroalloys Congress, INFACON X, (2004), 444-454.
- P. Argenta, C. Oertel, and B. Nourse, "Recent Development in Submerged Arc Smelting Technology," Steel and Metallurgy, November, (2008), 22-24.
- J. Sarvinis, N. Voermann, C. Crowe, J. Bianchini, and B. Wasmund, "Furnace Design for Modern, High-Intensity Pyrometallurgical Processes," Metallurgical Plant Design and Operating Strategies, Sydney, NSW, 15-16 April, 2002, AusIMM, 318-331.
- M. W. Kennedy, H. Haaland, J. A. Aune, "High Intensity Slag Resistance Furnace Design," Proceedings of the Conference of Metallurgists, Nickel-Cobalt 2009, CIM, Sudbury, Ontario, (2009) 101-110.
- A. Daenuwy, A. Dalvi, M. Solar, and B. Wasmund, "Development of Electric Furnace Design and Operation at PT Inco (Indonesia)," in International Symposium on Trace Metals and Furnace Practices in Non-Ferrous Pyrometallurgy, Met. Soc. of CIM, Edmonton, Alberta, (1992) 1-23.
- A. Matyas, R. Francki, K. Donaldson, and B. Wasmund, "Application of New Technology in the Design of High-Power Electric Smelting Furnaces," CIM bulletin, Vol. 86, (1993), 92-99.
- N. Voermann, V. Vaculik, T. Ma, C. Nichols, G. Roset, and W. Thurman, "Improvements to Stillwater Mining Company's Smelting Furnace Yielding Increased Capacity and Productivity," Sulfide Smelting'98: Current and Future Practices, (1998), 503-518.
- J. Sarvinis, S. De Vries, K. Joiner, C. Van Mierlo, N. Voermann, F. Stober, C. Rule, and P. Majoko, "Improvements to BHP Hartley Platinum's Smelting Furnace," Copper 99-Cobre 99, (1999), 613-628.
- L. Nelson, J. Geldenhuis, B. Emery, M. de Vries, K. Joiner, T. Ma, J. Sarvinis, F. Stober, R. Sullivan, and N. Voermann, "Hatch Developments in Furnace Design in Conjunction with Smelting Plants in Africa," Southern African Pyrometallurgy 2006, (2006), 417-436.
- F. Stober, T. Miraza, A. T. Hidyat, I. Jauhari, K. Belanger, D. Fowler, T. Gerritsen, A. Matyas, C. Nichols, and N. Voermann, "Furnace Upgrade with Hatch Technology at PT Antam FeNi-II in Pomalaa, Indonesia," INF ACON XI, New Delhi, India, (2007), 638-653.
- N. Voermann, T. Gerritsen, I. Candy, F. Stober, and A. Matyas, "Furnace Technology for Ferro-Nickel Production - an Update," International Laterite Nickel Symposium 2004, TMS Annual Meeting, (2004), 563-577.
- GDMB, "Heft 78, Feuerfestwesen in Metallhütten," Schriftenreihe der GDMB, (1997), 97-110.
- G. Ellefsen and Ø. Hallquist, "The Elkem Multi-Purpose Furnace® Used for Slag Production, Technical Description with Plant Features," presented at the Elkem seminar, Bhubaneswar, India, (1989), 1-17.
- J. Aune and O. Hallquist, "The Elkem Multipurpose Electric Smelter: A Cost Competitive Melt-Down Alternative," Recycle and Secondary Recovery of Metals, The Metallurgical Society of AIME, (1985), 833-855.
- H. Haaland, "Elkem Internal Report," (1986).
- Anonymous,"Elkem Internal Report," (1984).
- G. Bendzsak and W. Baines, "Analysis of Heat and Mass Transfer Mechanisms in Electric Smelting Furnaces," Proc. Int. Symp. on Non-ferrous Pyrometallurgy: Trace Metals, Furnace Practices, and Energy Efficiency. 31st Conf. Of Metallurgists, CIM, Edmonton, Canada, (1992), 373-391.
- A. Fallah-Mehrjardi, P. C. Hayes, and E. Jak, "Investigation of Freeze-Linings in Copper-Containing Slag Systems: Part I. Preliminary Experiments," Metallurgical and Materials Transactions B, Vol. 44, (2013), 534-548.
- H. Joubert, "Designing for Slag Freeze Linings on Furnace Sidewalls–an Engineering Perspective," Molten Slags, Fluxes and Salts, Stockholm, Sweden-Helsinki, (2000), 1-11.
- G. Eriksson and A. D. Pelton, "Critical Evaluation and Optimization of the Thermodynamic Properties and Phase Diagrams of the CaO-Al2O3, Al2O3-SiO2, and CaO-Al2O3-SiO2 Systems," Metallurgical Transactions B, Vol. 24, (1993), 807-816.
- D. Robertson and S. Kang, "Model Studies of Heat Transfer and Flow in Slag-Cleaning Furnaces," Fluid Flow Phenomena in Metals Processing, (1999), 157-168.
- S. Kang, "A Model Study of Heat Transfer and Fluid Flow in Slag-Cleaning Furnaces," Ph.D., University of Missouri-Rolla, (1992), 1-182.
- Y. Kang and K. Morita, "Thermal Conductivity of the CaO-Al2O3-SiO2 System," ISIJ International, Vol. 46, (2006), 420-426.
- T. Sakuraya, T. Emi, H. Ohta, and Y. Waseda, "Determination of Thermal-Conductivity of Slag Melts by Means of Modified Laser Flash Method," Journal of the Japan Institute of Metals, Vol. 46, (1982), 1131-1138.
- L. Zhang and S. Jahanshahi, "Review and Modeling of Viscosity of Silicate Melts: Part I. Viscosity of Binary and Ternary Silicates Containing CaO, MgO, and MnO," Metallurgical and Materials Transactions B, Vol. 29, (1998), 177-186.
- Y. Kang, K. Nomura, K. Tokumitsu, H. Tobo, and K. Morita, "Thermal Conductivity of the Molten CaO-SiO2-FeOx System," Metallurgical and Materials Transactions B, Vol. 43, (2012), 1420-1426.
- P. Richet, R. A. Robie, and B. S. Hemingway, "Thermodynamic Properties of Wollastonite, Pseudowollastonite and CaSiO3 Glass and Liquid," European Journal of Mineralogy, (1991), 475-484.
- M. Susa, M. Watanabe, S. Ozawa, and R. Endo, "Thermal Conductivity of CaO–SiO2–Al2O3 Glassy Slags: Its Dependence on Molar Ratios of Al2O3/CaO and SiO2/Al2O3," Ironmaking & Steelmaking, Vol. 34, (2007), 124-130.
- K. Nishioka, T. Maeda, and M. Shimizu, "Application of Square-Wave Pulse Heat Method to Thermal Properties Measurement of Cao-SiO2-Al2O3 System Fluxes," ISIJ International, Vol. 46, (2006), 427-433.
- S. Ozawa and M. Susa, "Effect of Na2O Additions on Thermal Conductivities of CaO–SiO2 Slags," Ironmaking & Steelmaking, Vol. 32, (2005), 487-493.
- Y. Fei, "Thermal Expansion," Mineral Physics and Crystallography: a Handbook of Physical Constants, Vol. 2, (1995), 29-44.
10.1029/RF002p0029 Google Scholar
- J. M. Bockris and D. Lowe, "Viscosity and the Structure of Molten Silicates," in Proceedings of the Royal Society of London A: Mathematical, Physical and Engineering Sciences, (1954), 423-435.
- G. Urbain, Y. Bottinga, and P. Richet, "Viscosity of Liquid Silica, Silicates and Alumino-Silicates," Geochimica et Cosmochimica Acta, Vol. 46, (1982), 1061-1072.
- K. Mills. ( accessed on-line, August 15, 2015). http://www.pyrometallurgy.co.za/kenmills/.
- G. Urbain, "Viscosity Estimation of Slags," Steel Research, Vol. 58, (1987), 111-116.
- K. Mills, L. Yuan, and R. Jones, "Estimating the Physical Properties of Slags," Journal of the Southern African Institute of Mining and Metallurgy, Vol. 111, (2011), 649-658.
- "Handbook of Refractory Practice," Harbison-Walker Refractories Company, Pittsburgh, USA, (2005), 1-331.
- R. Powell, C. Y. Ho, and P. E. Liley, "Thermal Conductivity of Selected Materials," NSRDS-NBS-8. National Standard Reference Data System, (1966), 1-175.
- M. W. Kennedy, P. Nos, M. Bratt, and M. Weaver, "Alternative Coolants and Cooling System Designs for Safer Freeze Lined Furnace Operation," Nickel-Cobalt 2013, (2013), 299-314.
10.1002/9781118658826.ch22 Google Scholar
- J. A. Aune, "Viscosity Balance in Slag Resistance Furnaces," Elkem, (2005), personal communication to M.W. Kennedy.