Formal Vinyl CH Activation and Allylic Oxidation by Olefin Metathesis
Arnab K. Chatterjee
Division of Chemistry and Chemical Engineering Arnold and Mabel Beckman Laboratories for Chemical Synthesis California Institute of Technology Mail Code 164-30, Pasadena, CA 91125 (USA) Fax: (+1) 626-564-9297
Search for more papers by this authorRobert H. Grubbs Prof. Dr.
Division of Chemistry and Chemical Engineering Arnold and Mabel Beckman Laboratories for Chemical Synthesis California Institute of Technology Mail Code 164-30, Pasadena, CA 91125 (USA) Fax: (+1) 626-564-9297
Search for more papers by this authorArnab K. Chatterjee
Division of Chemistry and Chemical Engineering Arnold and Mabel Beckman Laboratories for Chemical Synthesis California Institute of Technology Mail Code 164-30, Pasadena, CA 91125 (USA) Fax: (+1) 626-564-9297
Search for more papers by this authorRobert H. Grubbs Prof. Dr.
Division of Chemistry and Chemical Engineering Arnold and Mabel Beckman Laboratories for Chemical Synthesis California Institute of Technology Mail Code 164-30, Pasadena, CA 91125 (USA) Fax: (+1) 626-564-9297
Search for more papers by this authorGraphical Abstract
Stereoselective and chemoselective olefin cross metathesis can be viewed as a highly selective and efficient set of reactions that provide the same products as would selective CH activation and allylic oxidation (see scheme for an example). More active catalyst systems will provide an efficient process to functionalized products from readily available olefins. Cy=cyclohexyl.
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