Asymmetric Baeyer–Villiger Reaction with Hydrogen Peroxide Catalyzed by a Novel Planar-Chiral Bisflavin†
Shun-Ichi Murahashi Prof. Dr.
Department of Applied Chemistry, Faculty of Engineering Okayama University of Science 1-1, Ridaicho, Okayama 700-0005 (Japan) Fax: (+81) 86-256-9513
Search for more papers by this authorSatoshi Ono
Department of Applied Chemistry, Faculty of Engineering Okayama University of Science 1-1, Ridaicho, Okayama 700-0005 (Japan) Fax: (+81) 86-256-9513
Search for more papers by this authorYasushi Imada Prof. Dr.
Department of Chemistry, Graduate School of Engineering Science Osaka University 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan) Fax: (+81) 6-6850-6224
Search for more papers by this authorShun-Ichi Murahashi Prof. Dr.
Department of Applied Chemistry, Faculty of Engineering Okayama University of Science 1-1, Ridaicho, Okayama 700-0005 (Japan) Fax: (+81) 86-256-9513
Search for more papers by this authorSatoshi Ono
Department of Applied Chemistry, Faculty of Engineering Okayama University of Science 1-1, Ridaicho, Okayama 700-0005 (Japan) Fax: (+81) 86-256-9513
Search for more papers by this authorYasushi Imada Prof. Dr.
Department of Chemistry, Graduate School of Engineering Science Osaka University 1-3, Machikaneyama, Toyonaka, Osaka 560-8531 (Japan) Fax: (+81) 6-6850-6224
Search for more papers by this authorThis work was supported by the Research for the Future program, the Japan Society for the Promotion of Science.
Graphical Abstract
Der chirale Organokatalysator Bisflavin 1 katalysiert asymmetrische Baeyer-Villiger-Reaktionen von Cyclobutanonen mit H2O2 (siehe Schema). Die entsprechenden Lactone werden mit bis zu 74 % ee erhalten.
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