Observation of the Direct Products of Migratory Insertion in Aryl Palladium Carbene Complexes and Their Subsequent Hydrolysis†
Ana C. Albéniz Dr.
Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Valladolid Prado de la Magdalena s/n, 47005 Valladolid (Spain) Fax: (+34) 983-42-013
Search for more papers by this authorPablo Espinet Prof.
Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Valladolid Prado de la Magdalena s/n, 47005 Valladolid (Spain) Fax: (+34) 983-42-013
Search for more papers by this authorRaúl Manrique
Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Valladolid Prado de la Magdalena s/n, 47005 Valladolid (Spain) Fax: (+34) 983-42-013
Search for more papers by this authorAlberto Pérez-Mateo
Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Valladolid Prado de la Magdalena s/n, 47005 Valladolid (Spain) Fax: (+34) 983-42-013
Search for more papers by this authorAna C. Albéniz Dr.
Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Valladolid Prado de la Magdalena s/n, 47005 Valladolid (Spain) Fax: (+34) 983-42-013
Search for more papers by this authorPablo Espinet Prof.
Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Valladolid Prado de la Magdalena s/n, 47005 Valladolid (Spain) Fax: (+34) 983-42-013
Search for more papers by this authorRaúl Manrique
Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Valladolid Prado de la Magdalena s/n, 47005 Valladolid (Spain) Fax: (+34) 983-42-013
Search for more papers by this authorAlberto Pérez-Mateo
Departamento de Química Inorgánica Facultad de Ciencias, Universidad de Valladolid Prado de la Magdalena s/n, 47005 Valladolid (Spain) Fax: (+34) 983-42-013
Search for more papers by this authorThis work was supported by the Dirección General de Enseñanza Superior (Ministerio de Educación y Cultura, BQU2001-2015) and the Junta de Castilla y León (VA80/99 and VA17/00B). A fellowship from the Junta de Castilla y León to A.P.-M. is also acknowledged.
Graphical Abstract
Die Wechselwirkung eines elektrophilen Carben-Kohlenstoffatoms mit der π-Elektronendichte einer Arylgruppe führt dazu, dass 1 bevorzugt im Sinne einer intramolekularen Insertion reagiert (siehe Schema; Pf=C6F5). Die mit dieser Reaktion zugänglichen Alkylverbindungen (2 oder 3) können identifiziert werden, bevor sie letztendlich zu 4 hydrolysieren.
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