Rational Design of Homochiral Solids Based on Two-Dimensional Metal Carboxylates
Yong Cui Dr.
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorOwen R. Evans
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorHelen L. Ngo
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorPeter S. White Dr.
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorWenbin Lin Prof.
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorYong Cui Dr.
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorOwen R. Evans
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorHelen L. Ngo
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorPeter S. White Dr.
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorWenbin Lin Prof.
Department of Chemistry, CB#3290 University of North Carolina, Chapel Hill, NC 27599 (USA) Fax: (+1) 919-962-2388
Search for more papers by this authorWe acknowledge financial support from NSF (DMR-9875544). We thank Dr. Gary Enright for the X-ray powder diffraction patterns. W.L. is an Alfred P. Sloan Fellow, an Arnold and Mabel Beckman Young Investigator, a Cottrell Scholar of Research Corp, and a Camille Dreyfus Teacher-Scholar.
Graphical Abstract
Ein chirales 2D-Koordinationsnetzwerk bildet die Grundstruktur eines Zeolith-ähnlichen porösen Feststoffes mit Metall-Carboxylat-Koordination. Zum Aufbau werden enantiomerenreine Dicarboxylat-Brückenliganden verwendet. Eine Ethoxy-geschützte BINOL-Funktionalität ragt in die chiralen Hohlräume (siehe Bild).
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