Zuschrift

Hydroxylation of N-Heterocycle Ligands Observed in Two Unusual Mixed-Valence Cu^I/Cu^II Complexes

Xian-Ming Zhang

State Key Laboratory of Photoelectronic Materials& Technologies School of Chemistry and Chemical Engineering, Zhongshan University Guangzhou 510275 (China) Fax: (+86) 20-8411-2245

Search for more papers by this author

Ming-Liang Tong Dr.,

Ming-Liang Tong Dr.

State Key Laboratory of Photoelectronic Materials& Technologies School of Chemistry and Chemical Engineering, Zhongshan University Guangzhou 510275 (China) Fax: (+86) 20-8411-2245

Search for more papers by this author

Xiao-Ming Chen Prof. Dr.,

Xiao-Ming Chen Prof. Dr.

[email protected]

State Key Laboratory of Photoelectronic Materials& Technologies School of Chemistry and Chemical Engineering, Zhongshan University Guangzhou 510275 (China) Fax: (+86) 20-8411-2245

Search for more papers by this author

Xian-Ming Zhang,

Xian-Ming Zhang

State Key Laboratory of Photoelectronic Materials& Technologies School of Chemistry and Chemical Engineering, Zhongshan University Guangzhou 510275 (China) Fax: (+86) 20-8411-2245

Search for more papers by this author

Ming-Liang Tong Dr.,

Ming-Liang Tong Dr.

State Key Laboratory of Photoelectronic Materials& Technologies School of Chemistry and Chemical Engineering, Zhongshan University Guangzhou 510275 (China) Fax: (+86) 20-8411-2245

Search for more papers by this author

Xiao-Ming Chen Prof. Dr.,

Xiao-Ming Chen Prof. Dr.

[email protected]

State Key Laboratory of Photoelectronic Materials& Technologies School of Chemistry and Chemical Engineering, Zhongshan University Guangzhou 510275 (China) Fax: (+86) 20-8411-2245

Search for more papers by this author

First published: 15 March 2002

https://doi.org/10.1002/1521-3757(20020315)114:6<1071::AID-ANGE1071>3.0.CO;2-V

Citations: 45

This work was supported by the National Natural Science Foundation of China (nos. 20131020, 29971033, 20001008) and the Foundation for University Key Teacher of the Ministry of Education. We thank Prof. Song Gao at Peking University for the magnetic measurement.

Share a link

Email
Wechat
Bluesky

Graphical Abstract

Belege für den Gillard-Mechanismus der Bildung „kovalenter Hydrate“ bieten die Strukturen zweier gemischtvalenter Cu^I/Cu^II-Komplexe mit 2,2′-Bipyridin- (siehe Bild) oder 1,10-Phenanthrolinliganden, bei denen eine Hydroxygruppe an ein Kohlenstoffatom neben einem Stickstoffatom gebunden ist. Diese Komplexe wurden durch Hydrothermalsynthese aus Cu(NO₃)₂, dem jeweiligen N,N-Liganden und Terephthalsäure erhalten.

References

1 C. Kaes, A. Katz, M. W. Hosseini, Chem. Rev. 2000, 100, 3553–3590.
10.1021/cr990376z
CAS PubMed Web of Science® Google Scholar
2 K. Warnmark, J. A. Thomas, O. Heyke, J.-M. Lehn, Chem. Commun. 1996, 701–702.
10.1039/CC9960000701
Web of Science® Google Scholar
3 R. D. Gillard, Coord. Chem. Rev. 1975, 16, 67–94.
10.1016/S0010-8545(00)80285-4
CAS Web of Science® Google Scholar
4 M. S. Henry, M. Z. Hoffman, J. Am. Chem. Soc. 1977, 99, 5201–5203;
10.1021/ja00457a062
CAS Web of Science® Google Scholar
M. S. Henry, M. Z. Hoffman, J. Phys. Chem. 1979, 83, 618–625.
10.1021/j100468a012
CAS Web of Science® Google Scholar
5 A. Gameiro, R. D. Gillard, M. M. R. Bakhsh, N. H. Rees, Chem. Commun. 1996, 2245–2246.
10.1039/CC9960002245
CAS Web of Science® Google Scholar
6 N. Serpone, G. Ponterini, M. A. Jamieson, Coord. Chem. Rev. 1983, 50, 209–302;
10.1016/0010-8545(83)80021-6
CAS Web of Science® Google Scholar
O. Farver, O. Monsted, G. Nord, J. Am. Chem. Soc. 1979, 101, 6118–6120;
10.1021/ja00514a044
CAS Web of Science® Google Scholar
W. A. Wickramasinghe, P. H. Bird, M. A. Jamieson, N. Serpone, J. Chem. Soc. Chem. Commun. 1979, 798–800.
10.1039/C39790000798
CAS Web of Science® Google Scholar
7 D. Dandrini, M. T. Gandolfi, L. Moggi, V. Balzani, J. Am. Chem. Soc. 1978, 100, 1463–1468;
10.1021/ja00473a022
Web of Science® Google Scholar
E. C. Constable, Polyhedron 1983, 2, 551–572, and references therein.
10.1016/S0277-5387(00)81511-9
CAS Web of Science® Google Scholar
8 E. C. Constable, Metals and Ligand Reactivity, VCH, Weinheim, 1996, pp. 245–262.
Web of Science® Google Scholar
9 S. M.-F. Lo, S. S.-Y. Chui, L.-Y. Shek, Z.-Y. Lin, X.-X. Zhang, G.-H. Wen, I. D. Williams, J. Am. Chem. Soc. 2000, 122, 6293–6294.
10.1021/ja000416c
CAS Web of Science® Google Scholar
10 C. Harding, V. Mckee, J. Nelson, J. Am. Chem. Soc. 1991, 113, 9684–9685.
10.1021/ja00025a050
CAS Web of Science® Google Scholar
11 M. E. Barr, P. H. Smith, W. E. Antholine, B. Spencer, Chem. Commun. 1993, 1649–1652.
10.1039/C39930001649
CAS Web of Science® Google Scholar
12 R. P. Houser, V. G. Young, W. B. Tolman, J. Am. Chem. Soc. 1996, 118, 2101–2102.
10.1021/ja953776m
CAS Web of Science® Google Scholar
13 F. Neese, W. G. Zumft, W. E. Antholine, P. M. H. Kroneck, J. Am. Chem. Soc. 1996, 118, 8692–8699.
10.1021/ja960125x
CAS Web of Science® Google Scholar
14 D. D. LeCloux, R. Davydov, S. J. Lippard, J. Am. Chem. Soc. 1998, 120, 6810–6811.
10.1021/ja9805021
CAS Web of Science® Google Scholar
15 A mixture of phen (0.117 g) or bpy (0.102 g), H₂tp (0.041 g), NaOH (0.02 g), and water (10 mL) in the molar ratio 1.3:0.25:0.5:1100 was sealed in 23-mL Teflon reactor, which was heated in an oven at 160 °C for 144 h. No solid hydroxylated organic product was observed.
Google Scholar
16 Crystal data for 3: monoclinic, space group P2₁/n, M_r=517.47, a=10.651(8), b=6.180(4), c=15.079(13) Å, β=94.160(10)°, V=989.9(13) Å³, Z=2.
Google Scholar
17 S. Ferguson-Miller, G. T. Babcock, Chem. Rev. 1996, 96, 2889–2907;
10.1021/cr950051s
CAS PubMed Web of Science® Google Scholar
G. A. Baranovic, J. Coyle, C. G. Coates, J. J. McGarvey, V. McKee, J. Nelson, Inorg. Chem. 1998, 37, 3567–3574;
10.1021/ic971274z
PubMed Web of Science® Google Scholar
S. Iwata, C. Ostermeier, B. Ludwig, H. Michel, Nature 1995, 376, 660–669;
10.1038/376660a0
CAS PubMed Web of Science® Google Scholar
T. Tsukihara, H. Aoyama, E. Yamashita, T. Tomizaki, H. Yamaguchi, K. Shinzawa-Itoh, R. Nakahima, R. Yaono, S. Yoshikawa, Science 1996, 272, 1136–1144.
10.1126/science.272.5265.1136
CAS PubMed Web of Science® Google Scholar
18 General crystallographic information: Mo_Kα radiation (λ=0.71073 Å). T=293 K. Siemens R3m diffractometer, ω scan mode (4≤2θ≤52° for 1 and 4≤2θ≤52° for 2), solved with direct methods (SHELXS-97)^[19] and refined with full-matrix least-squares (SHELXL-97).^[20] CCDC-170016 and CCDC-170017 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or [email protected]).
Google Scholar
19 G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, Göttingen University, Germany, 1997.
Google Scholar
20 G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, Göttingen University, Germany, 1997.
Google Scholar

Citing Literature

Volume114, Issue6

March 15, 2002

Pages 1071-1073

This is the

German version

of Angewandte Chemie.

Note for articles published since 1962:

Do not cite this version alone.

Take me to the International Edition version with citable page numbers, DOI, and citation export.

We apologize for the inconvenience.

Hydroxylation of N-Heterocycle Ligands Observed in Two Unusual Mixed-Valence Cu^I/Cu^II Complexes

Graphical Abstract

References

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Hydroxylation of N-Heterocycle Ligands Observed in Two Unusual Mixed-Valence CuI/CuII Complexes

Graphical Abstract

References

Citing Literature

References

Related

Information

Hydroxylation of N-Heterocycle Ligands Observed in Two Unusual Mixed-Valence Cu^I/Cu^II Complexes