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Cover Picture
Nanosuspensions: Small 8/2009
- First Published: 08 April 2009

The cover picture illustrates the synthesis of dextran biopolymer stabilized metal oxide nanosuspensions prepared by precipitation in dextran solutions followed by dextranase enzymatic deshelling by endohydrolysis of the dextran into oligomers and maltoses to liberate the metal oxide nanoparticles. A low level of surface remant oligomer remains to prevent subsequent aggregation and growth of the nanoparticles whilst still freeing the nanoparticle surface for activity. The green synthetic process described is suitable for scale up as a biosynthetic and moderated precipitation route to a wide range of functional nanoparticles. For more information, please read the Communication “Controlled Nanoparticle Formation by Enzymatic Deshelling of Biopolymer-Stabilized Nanosuspensions” by D. Walsh et al. beginning on page 913. Dextranase structure courtesy of PDB database taken from A. M. Larsson, R. Andersson, J. Stahlberg, L. Kenne, T. A. Jones, Structure, 2003, 11, 1111.
Inside Cover
Interfaces: Small 8/2009
- First Published: 08 April 2009

The cover picture illustrates the direct imaging of the microscopic water/air/solid three-phase interface of a hierarchical micro/nanoscale lotus leaf surface by the “droplet-inside-view” method. A water-droplet presents the typical profile when contacting with the superhydrophobic surface of lotus leaves (shown in the center of picture). This superhydrophobic state can be clearly shown at the microscopic scale by environmental scanning electron microscopy (top left corner). The atomic force microscopy (AFM) cantilever with its probe is then immerged within the water droplet to scan over the internal water/air/solid interface between the water droplet and lotus leaf surface (shown top right corner). This method may enable the quantitive description of the water/air/solid three-phase interface at hierarchical micro/nanoscales by using AFM imaging and force-curve analysis. For more information, please read the Communication “Wetting Behavior at Micro-/Nanoscales: Direct Imaging of a Microscopic Water/Air/Solid Three-Phase Interface” by D. Han, L. Jiang, et al. beginning on page 908.
Contents
News
Review
Electromagnetism
Nanoelectromagnetics: Circuit and Electromagnetic Properties of Carbon Nanotubes
- Pages: 884-906
- First Published: 08 April 2009

The contribution of carbon nanotubes as the building block of high-frequency electronic devices has received much interest due to their favorable characteristics. This Review focuses on the electromagnetic properties (see image) of individual as well as multiple- and single-walled carbon-nanotube arrangements primarily aimed at microwave, millimeter-wave, and THz electronics applications.
Communications
Interfaces
Wetting Behavior at Micro-/Nanoscales: Direct Imaging of a Microscopic Water/Air/Solid Three-Phase Interface†
- Pages: 908-912
- First Published: 08 April 2009

Direct imaging of water/air/solid interfaces: A “droplet-inside-view” method based on MAC-mode AFM and force–volume function is introduced to directly characterize the microscopic details of a three-phase interface. Researches of the Cassie state, the quasi-Wenzel state, and the transition of the two states for lotus leaves show (see image) that microscopic wetting behavior dominates the macroscopic wettability of micro-/nanoscale interfaces.
Nanosuspensions
Controlled Nanoparticle Formation by Enzymatic Deshelling of Biopolymer-Stabilized Nanosuspensions†
- Pages: 913-918
- First Published: 08 April 2009

Formation of biopolymer-stabilized nanosuspensions followed by dextranase enzyme treatment is demonstrated for the liberation of monodisperse particles of controllable size up to 6 nm (see image). A range of metal oxide nanoparticles stabilized by remnant oligomer at ≈3 wt% are reliably prepared for applications that include catalysis and nanoparticle-based biosensors.
Lithography
Structured Polymer Brushes by AFM Lithography†
- Pages: 919-923
- First Published: 08 April 2009

Structured polymer brushes are readily prepared by AFM lithography and show improved mechanical properties over structured polymer films obtained on spin-coated films by using the same method. The figure shows an array of 200-nm-diameter pillars obtained on a 30-nm-thick polystyrene brush by cross writing of single scan lines.
Graphene nanoribbons
Ultralong Natural Graphene Nanoribbons and Their Electrical Conductivity†
- Pages: 924-927
- First Published: 08 April 2009

An atomic force microscopy topograph with a long and narrow (≈24 µm × 37 nm) graphene nanoribbon emerging from a graphite flake laying on a silicon oxide substrate is shown in the image. The sample is prepared by microcleavage using silicone stamps instead of cellophane tape. These nanoribbons present well-defined edges along the graphite crystallographic directions.
Pattern transfer
Large-Area Dual-Scale Metal Transfer by Adhesive Force†
- Pages: 928-932
- First Published: 08 April 2009

A dual-scale metal transfer technique is presented to generate metal patterns with two different length scales from a single master. An adhesive polymer layer is brought in contact with the metal-coated surface in two sequential steps to transfer metal layers from both ridges and valleys of the mold aided by the difference in adhesive force (see image).
Semiconductor nanomaterials
Thermal and Electrical Conductivity of Size-Tuned Bismuth Telluride Nanoparticles†
- Pages: 933-937
- First Published: 08 April 2009

Size-tuned thiol-capped bismuth telluride nanoparticles (see image) are synthesized and annealed to make phase-pure nanostructured material. These materials exhibit relatively high thermoelectric power and unusually low temperature-independent thermal conductivity, the latter due to phonon scattering.
Full Papers
Quantum dots
Site-Controlled InGaAs Quantum Dots with Tunable Emission Energy
- Pages: 938-943
- First Published: 08 April 2009

Size (and position) matters: Site-controlled InGaAs quantum dots (QDs) of high homogeneity are grown on (111)B GaAs substrates patterned with submicrometer inverted pyramids (see AFM images). The strong dependence of the QD emission energy, EQD, on the pyramids' position and size is investigated, and the possibility of using this dependence to fine-tune EQD is discussed.
Nanocomposites
Electrospun Nanoparticle–Nanofiber Composites via a One-Step Synthesis
- Pages: 944-951
- First Published: 08 April 2009

Electrospun nanoparticle–nanofiber composites (see image) are fabricated via a one-step synthesis wherein the electrospun polymer acts as both a reducing agent for the metal salt precursor and a protecting and templating agent for the ensuing nanoparticles. The in situ reduction is done under ambient conditions and is free of organic solvents and separate chemical reducers and stabilizers.
Polymer-blend films
Nanoscale Probing of a Polymer-Blend Thin Film with Tip-Enhanced Raman Spectroscopy
- Pages: 952-960
- First Published: 08 April 2009

A useful tip: Tip-enhanced Raman spectroscopy reveals a wealth of chemical and structural information on a polymer-blend thin film with high lateral and depth resolution (see picture). The location of the polymers and local differences in the thickness of the films, as well as nanopores at the subsurface of the polymer film are detected.
Nanoparticles
Advancements Toward the Greener Processing of Engineered Nanomaterials—Effect of Core Size on the Dispersibility and Transport of Gold Nanocrystals in Near-Critical Solvents†
- Pages: 961-969
- First Published: 08 April 2009

The dispersion/precipitation process of gold nanocrystals in near-critical fluids (NcFs) can be fine-tuned by discrete variations in the fluid density and is largely dependent upon nanoparticle size. Larger nanocrystal cores lose dispersibility faster as density is decreased. The results show that size-selective transport, separation, and deposition of nanocrystals are possible in NcFs by choosing the appropriate solvent and density range (see image).
Photoswitchable nanoparticles
Photoreversible Fluorescent Modulation of Nanoparticles via One-Step Miniemulsion Polymerization
- Pages: 970-978
- First Published: 08 April 2009

Polymeric nanoparticles containing a fluorescent dye and a photochromic spiropyran are prepared via a facile one-step miniemulsion polymerization (see image). UV and visible light can be applied to reversibly “switch on” and “switch off” the fluorescence emission of the fluorescent dye through the intraparticle fluorescence resonance energy-transfer process.