Heteroatom Chemistry: Vol 17, No 3

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Heteroatom Chemistry

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[1-Me-1-closo-SnB₁₁H₁₁]⁻ as a potential weakly coordinating anion: Synthesis of Rh(PPh₃)₂(1-Me-closo-SnB₁₁H₁₁) and comparisons with Rh(PR₃)₂ (1-H-closo-CB₁₁ H₁₁)

Tetrabutylammonium salt of the B₂₄F₂₂⁴⁻ anion. Two B₁₂F₁₁²⁻ icosahedra linked by a 2c–2e BB bond and surrounded by a sheath of CH· · ·FB hydrogen bonds

Metallacyclopentadienes and related heterocycles via 1,1-organoboration of alkyn-1-ylmetal compounds

Synthesis and structure of the coordinatively unsaturated boron subphthalocyanine cation, [B(SubPc)]⁺

Preparation of undecamethylated and hexamethylated 1-halocarba-closo-dodecaborate anions

(π+σ)-double aromatic and π,σ-mixed aromatic boron compounds with two electrons delocalized over three centers

Reactivity of terminal transition metal borylene complexes ^†

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[1-Me-1-closo-SnB11H11]− as a potential weakly coordinating anion: Synthesis of Rh(PPh3)2(1-Me-closo-SnB11H11) and comparisons with Rh(PR3)2 (1-H-closo-CB11 H11)

Tetrabutylammonium salt of the B24F224− anion. Two B12F112− icosahedra linked by a 2c–2e BB bond and surrounded by a sheath of CH· · ·FB hydrogen bonds

Metallacyclopentadienes and related heterocycles via 1,1-organoboration of alkyn-1-ylmetal compounds

Synthesis and structure of the coordinatively unsaturated boron subphthalocyanine cation, [B(SubPc)]+

Preparation of undecamethylated and hexamethylated 1-halocarba-closo-dodecaborate anions

(π+σ)-double aromatic and π,σ-mixed aromatic boron compounds with two electrons delocalized over three centers

Reactivity of terminal transition metal borylene complexes†

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[1-Me-1-closo-SnB₁₁H₁₁]⁻ as a potential weakly coordinating anion: Synthesis of Rh(PPh₃)₂(1-Me-closo-SnB₁₁H₁₁) and comparisons with Rh(PR₃)₂ (1-H-closo-CB₁₁ H₁₁)

Tetrabutylammonium salt of the B₂₄F₂₂⁴⁻ anion. Two B₁₂F₁₁²⁻ icosahedra linked by a 2c–2e BB bond and surrounded by a sheath of CH· · ·FB hydrogen bonds

Synthesis and structure of the coordinatively unsaturated boron subphthalocyanine cation, [B(SubPc)]⁺

Reactivity of terminal transition metal borylene complexes ^†