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Figure 3 Unit-cell projection of the Ca(H2O)4(BF4)2 structure along the b axis, showing the intricate hydrogen-bonding scheme, with both O—H⋯F and O—H⋯O hydrogen bonds maintaining in 3D the 1D ribbons built from [CaO4F4] square antiprisms sharing F corners with [BF4] tetrahedra. |