Volume 649, Issue 6-7 e202300039
Cover Picture
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Front Cover: Copper(I) and Gold(I) Complexes of Aminofunctionalized Phosphinines: Synthesis and Structural Characterization (Z. Anorg. Allg. Chem. 6-7/2023)

Jinxiong Lin

Jinxiong Lin

Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany

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Dr. Daniel S. Frost

Dr. Daniel S. Frost

Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany

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Dr. Nathan T. Coles

Dr. Nathan T. Coles

Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany

School of Chemistry, University of Nottingham, University Park Campus, NG7 2RD Nottingham, UK

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Manuela Weber

Manuela Weber

Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany

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Prof. Dr. Christian Müller

Corresponding Author

Prof. Dr. Christian Müller

Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany

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First published: 03 April 2023

Graphical Abstract

The cover picture shows the solid-state structure of an unusual Cu4-rhombus, which is capped by a total of four chlorido ligands. Two aminofunctionalized, aromatic phosphinines coordinate in the classical σ-coordination mode via the phosphorus lone pair to two of the four Cu(I) centers. The other two phosphinines show a rare bridging μ2-coordination mode and span two of the four Cu(I) centers. (DOI: 10.1002/zaac.202200365).

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