Enhancing FAPbI₃ Perovskite Solar Cell Performance and Stability Through Bespoke Graphene Quantum Dots

2.1 Synthesis of Bespoke GQDs Tuned by Alkylamines

GQDs functionalized with amines of varying alkyl chain lengths, including butylamine (BA), octylamine (OA), and dodecylamine (DDA), were synthesized through the Amadori reaction with glucose [21, 22]. Figure 1A–C shows the morphology of the synthesized GQDs as observed through transmission electron microscopy (TEM) analysis. As the alkyl chain length of the amine increases, the average size of particles of GQDs tends to decrease: C4 is 6.82 nm, C8 is 2.91 nm, and C12 is 2.68 nm. (Figure S1) The inset images in each TEM image reveal a lattice spacing of 0.21 nm, corresponding to the in-plane (100) facet of graphene, confirming the synthesis of GQDs. The decrease in GQDs particle size with longer alkyl chain lengths is attributed to the steric hindrance caused by the long alkyl chains obstructs the crystal growth of GQDs from the Amadori products, preventing the particles from growing beyond a certain size over time, as shown in Figure S2 [23]. Further confirmation of the synthesis was obtained through UV–Vis and photoluminescence (PL) spectra analyses, as shown in Figure S3, where all three types of GQDs exhibited strong absorption peaks at around 280 nm and 350 nm, typical of the ππ* transition of sp²-bonded carbon and the nπ* transitions of CO and CN groups. The PL spectra also showed excitation-dependent emission, with consistent changes in wavelength, which are characteristic of GQDs [24]. These results confirm that the GQDs were successfully synthesized.

To investigate the effect of alkyl chain length in alkyl amines on the properties of GQDs, we conducted Fourier transform infrared (FT–IR) and Raman analyses, as shown in Figure 1D,E. In the FT–IR spectra, all three samples had characteristic peaks of asymmetric and symmetric CH₂ stretches (2922 and 2856 cm⁻¹), OH and NH stretches (3293 cm⁻¹), CC aromatic ring stretches (1473, 1565, and 1666 cm⁻¹), CO stretches (1666 cm⁻¹), overlap with ring stretching region, and in-plane and out-plane CH ring structure bending (726 and 1037 cm⁻¹). As the alkyl chain length of the alkylamine increases, more pronounced peaks are observed in the CH stretches, which suggests that longer alkylamines are progressively binding as functional groups on the surface of the GQDs, consistent with previously reported findings [25]. Additionally, x-ray photoelectron spectroscopy (XPS) analysis was performed on the GQDs. According to Figure S4A, the GQDs are primarily composed of C, N, and O, and as alkyl chain length increases, the N/C ratio decreases from 0.1 for C4 to 0.08 for C8 and 0.05 for C12. Furthermore, the CN peak observed in the C1s spectra in Figure S4B and the peaks present in the N1s spectra in Figure S4C suggest that alkylamines with different alkyl chain lengths are present in each sample.

In the Raman spectra shown in Figure 1E, two distinct peaks at approximately 1364 and 1588 cm⁻¹ correspond to the D band and G band, respectively, arising from the out-of-plane vibration of sp³ carbons and the in-plane vibration of sp² carbons [26]. The intensity ratio of the D band and to the G band (I_D/I_G) was measured to be 0.92, 0.89, and 0.86 for C4, C8, and C12, respectively. All three samples generally exhibit low I_D/I_G ratios, indicating a low level of defects. However, as the alkyl chain length increases, the I_D/I_G ratio gradually decreases. This suggests, as observed in the TEM analysis, that the degree of defects decreases as the particle size becomes smaller [27]. Based on these results, it was confirmed that all three samples were successfully synthesized and alkylamines of varying lengths effectively incorporated as functional groups.

2.2 Effects of AA-GQDs at the Interface

First, to analyze the changes in the perovskite crystal according to the characteristics of SnO₂ treated with AA-GQDs, scanning electron microscopy (SEM), contact angle, and X-ray diffraction (XRD) patterns were analyzed. As shown in Figure S7, we used rutile SnO₂ with the (110) plane of 3.06 nm [29]. The AA-GQDs treated SnO₂ were uniformly coated on the surface as the hydrophilicity of AA-GQDs increased, and the wettability of SnO₂ was also enhanced (Figure S8).

To investigate the impact of GQDs synthesized with alkylamines of varying chain lengths on charge dynamics at PSC interfaces, we introduced GQDs at each interface, observed the resulting changes in optical and electrical properties, and optimized the system as shown in Figure 2. The perovskite films deposited on SnO₂ and AA-GQDs treated SnO₂ were analyzed by SEM images and XRD patterns (Figures S9 and S10). It was confirmed that the perovskite deposited on SnO₂ and AA-GQDs treated SnO₂ had similar grain sizes and film thicknesses, and they were confirmed that highly crystalline FAPbI₃ was formed. We also applied 10 wt.% of GQDs with different alkylamines to the SnO₂ ETL/perovskite and perovskite surfaces to quickly identify the most suitable GQDs for each layer. As shown in Figure S11, the PL spectra in Figure S11A and the time-resolved photoluminescence (TRPL) spectra in Figure S11B indicate that C4-GQDs provide the most efficient charge extraction, attributed to the increased conductivity of SnO₂ (Figure S11C). Thus, C4-GQDs were identified as the best for enhancing charge transfer at the SnO₂ ETL/perovskite interface. Conversely, applying C12-GQDs on the perovskite surface reduced traps, as evidenced by the lower V_TFL in space-charge-limited current (SCLC) measurements (Figure S11D), leading to the highest PL intensity and longest TRPL decay time, confirming effective defect passivation [20]. (Figure S11E and S11F) Therefore, C4-GQDs and C12-GQDs were found to be suitable for their respective interfaces.

Based on the initial screening experiments, we selected the most suitable AA-GQDs for each interface. To optimize PSCs performance through the introduction of GQDs at each interface, we systemically evaluated the device characteristics by varying the concentrations of the selected GQDs. First, we aimed to optimize the SnO₂/perovskite interface by treating SnO₂ with C4-GQDs. We conducted UPS analysis on samples with varying concentrations, as shown in Figure S12A, to observe how the band energy structure of SnO₂ ETL changes. From this analysis, we calculated the band energy structure of SnO₂ ETL and presented the results in Figure 2A. As C4-GQDs, which have a higher Fermi level than SnO₂, were applied at increasing concentrations, the Fermi level of SnO₂ also shifted upward. Additionally, the electrical conductivity increased due to the higher conductivity of C4-GQDs compared to SnO₂, as shown in Figure S12B.

The changes in charge dynamics were analyzed through PL and TRPL measurements of the SnO₂ ETL/perovskite interface treated with varying concentrations of C4-GQDs, as shown in Figure 2B,C. In Figure 2B, the PL intensity significantly decreases when the SnO₂/perovskite interface is formed, with the lowest intensity observed at 10 wt.% C4-GQDs in the SnO₂ ETL. This reduction is attributed to minimized energy offset between the conduction bands of the SnO₂ ETL and the perovskite layer, along with improved conductivity that enhances charge extraction. However, at 15 wt.%, the PL intensity slightly increases as the conduction band of the SnO₂ ETL rises above that of the perovskite layer. This trend is further confirmed in the TRPL spectra shown in Figure 2C, where the fastest PL decay was observed at a C4-GQDs concentration of 10 wt.%. Therefore, the introduction of 10 wt.% C4-GQDs between the SnO₂ ETL and perovskite layer is expected to minimize the energy offset and increase conductivity, thereby improving charge transfer properties at the SnO₂/perovskite interface, reducing electron losses in PSCs, and ultimately contributing to enhanced open-circuit voltage (V_oc).

The differences in the perovskite films according to the C12-GQD treatment were analyzed by the top SEM images and XRD. As shown in Figure S13A, the XRD patterns showed that both samples have similar crystallinity. In contrast, the SEM images showed that the C12-GQDs sample has relatively larger crystal grains than the control sample as we reported in the previous paper [30] (Figure S13B,C). The perovskite grain boundaries grew smoothly with the treatment of C12-GQDs, resulting in larger grains compared to samples without C12-GQDs [31]. This is because the C12-GQDs coated on the perovskite healed the grains and bulk of the perovskite during the annealing process [30]. The trap passivation effect of perovskite surface treatment with varying concentrations of C12-GQDs was analyzed through SCLC measurements using hole-only devices (ITO/PTAA/perovskite/C12-GQDs/spiro-OMeTAD/Au), as shown in Figure 2D. The SCLC results indicate that as the concentration of C12-GQDs increases, the V_TFL shifts to lower voltages, saturating at 20 wt.%, indicating effective defect passivation and reduced trap density. As shown in Figure 2E, the PL intensity of the perovskite film increases noticeably up to 20 wt.% C12-GQDs, with a slight increase at 30 wt.%. This trend is consistent with the TRPL results in Figure 2F and aligns with the SCLC measurements. In contrast, when the perovskite forms a junction with spiro-OMeTAD HTL, the PL intensity decreases sharply, remaining stable up to 20 wt.% C12-GQDs before increasing at higher concentrations. Similarly, TRPL measurements show rapid PL decay when forming a junction with spiro-OMeTAD, with consistent decay rates up to 20 wt.% C12-GQDs and a slight increase at 30 wt.%. These findings suggest that up to 20 wt.%, C12-GQDs enable effective trap passivation and efficient hole transfer to spiro-OMeTAD HTL, but higher concentrations impede hole transfer due to the long alkyl chains of C12-GQDs. Thus, introducing 20 wt.% C12-GQDs between the perovskite and spiro-OMeTAD effectively passivates defects by sharing lone pair electrons from nitrogen and oxygen atoms on GQDs edges with undercoordinated Pb²⁺ ions in the perovskite layer, without hindering hole transfer [32].

2.3 Optimizing Performance Enhancement Using Bespoke GQDs

To systematically investigate the effect of tailored GQDs application at different interfaces, specifically the ETL/perovskite and perovskite/HTL interfaces, on device efficiency, we fabricated PSCs with the structure of ITO/SnO₂/perovskite/spiro-OMeTAD/Au, which serves as the basic structure for the control device, as shown in Figure S14. Figure 3A presents the forward and reverse J–V curves for three types of devices: the control device with the basic structure, the GT-SnO₂ device with GQDs-embedded ETL/perovskite interface structure, and the BiT device with GQDs-embedded ETL/perovskite and GQDs applied to perovskite/HTL interfaces. Notably, the modification of these interfaces resulted in a significant increase in V_oc and FF. The control device exhibited a V_oc of 1.11 V, a short-circuit current density (J_sc) of 24.60 mA/cm², an FF of 80.98%, and a PCE of 21.91%. After interface modification by embedding GQDs at the ETL/perovskite interface, the PCE increased to 23.78%, primarily due to a significant increase in V_oc and FF, which improved to 1.15 V and 83.05%, respectively. This enhancement in V_oc and FF, as previously observed in perovskite thin films, is attributed to the reduction in energy level offset between the conduction band energies of SnO₂ ETL and perovskite layer, as well as the increased conductivity resulting from GQDs embedded at the ETL/perovskite interface. Further with the dual modification at the perovskite/HTL interface, all photovoltaic parameters showed additional improvements, leading to an outstanding PCE of 24.41% in the BiT device. This enhancement is attributed to the reduction in trap density at the perovskite/HTL interfaces. The trap density reduction is primarily due to the effective passivation of defects by GQDs, which interact with undercoordinated Pb²⁺ ions at the surface and grain boundaries of the perovskite film, neutralizing these defects and leading to improved device performance [20, 30]. This PCE is particularly promising when compared to other n-i-p structured perovskite devices using carbon-based materials (Table S1). These changes in photovoltaic parameters are further illustrated by the photovoltaic parameters distribution of 50 devices shown in Figure S15. The best-performing photovoltaic parameters for each device and the average photovoltaic parameters across 50 samples are summarized in Table S2.

The changes in PCE related to the optimization of GQDs applied at each interface are shown in Figures S16 and S17. For the SnO₂ ETL/perovskite interface, the optimal GQDs amount was determined to be 10 wt.%. While increasing the GQDs content improved the conductivity of the SnO₂ ETL, the efficiency decreased at 15 wt.% because the conduction band of the SnO₂ ETL rose above that of the perovskite layer. At the perovskite/HTL interface, the highest efficiency was achieved at 20 wt.%, where defect passivation increased with GQDs concentration but reached saturation between 20 wt.% and 30 wt.%. However, the long alkyl chain with 12 carbon atoms hinders charge transfer between the interfaces, creating a trade-off between the positive effects of trap passivation and the negative effects of long alkyl chains on inhibited charge transfer [30]. Therefore, 10 wt.% at the ETL interface and 20 wt.% at the HTL interface were determined to be the most effective amounts.

Figure 3B shows the stabilized power output (SPO) at the maximum power point (MPP) for the control, GT-SnO₂, and BiT devices. Under continuous illumination, the stabilized PCE significantly increased from 21.90% in the control device to 24.08% in the BiT device, following interface treatment. This value closely aligns with the forward scan efficiency of each device.

The external quantum efficiency (EQE) spectra and the corresponding integrated J_sc are displayed in Figure 3C. The integrated J_sc values are 24.22, 24.55, and 24.71 mA/cm² for the devices with the structure of control, GT-SnO₂, and BiT, respectively. The minimal discrepancy between the J_sc values determined from the EQE spectra and the J–V curves indicates that the J–V curve measurements were performed accurately.

To gain deeper insights into the reasons behind the enhanced performance, we investigated the electrical properties of the control, GT-SnO₂, and BiT devices. The light intensity-dependent V_oc and J_sc measurements for these devices are presented in Figure 3D,E. The ideality factor (n) was determined from the slope of V_oc measured under varying light intensities ranging from 10 to 100 mW/cm². The ideality factor is indicative of the recombination process, where values closer to 1 suggest a dominance of trap-assisted recombination. The ideality factors obtained were 1.48 for the control device, 1.37 for the GT-SnO₂ device, and 1.31 for the BiT device, indicating that non-radiative recombination was effectively suppressed in the presence of GQDs, correlating with the observed increase in V_oc. Similarly, the alpha coefficient (α) was derived from the light intensity-dependent J_sc measurements, reflecting the charge recombination characteristics. An α value near unity suggests that bimolecular recombination is the prevailing mechanism for electron–hole pairs. As GQDs were incorporated at each interface, the α values progressively approached unity, suggesting an increasing dominance of radiative recombination.

Additionally, electrochemical impedance spectroscopy (EIS) was performed to investigate carrier dynamics in the working devices. The Nyquist plot, recorded in the dark under short-circuit condition (0 V), and the near-open-circuit condition (1.1 V) for the control, GT-SnO₂, and BiT devices, are shown in Figure 3F. The low-frequency response, which correlates with carrier recombination at the interface, reveals that larger semicircles correspond to stronger charge recombination resistance (R_rec). The extracted R_rec values obtained were 1.36, 2.07, and 2.56 kΩ at 0 V for the control, GT-SnO₂, and BiT devices, respectively, and 28.64, 23.55, and 15.73 kΩ at 1.1 V for the control, GT-SnO₂, and BiT devices, respectively. The gradual increase in R_rec with the introduction GQDs for interface modification confirms enhanced resistance to interfacial recombination.

Furthermore, Mott–Schottky measurements were conducted to determine the built-in potential (V_bi). The capacitance–voltage (C–V) curves are shown in Figure 3G, with the V_bi being inferred from the intersection with the x-axis. It is evident that the V_bi significantly increases (from 1.04 in the control to 1.08 and 1.11 V for GT-SnO₂ and BiT, respectively), indicating that interface modification effectively enhances the separation, transport, and extraction of photogenerated charge carriers.

Overall, the strategic incorporation of GQDs at the ETL/perovskite and perovskite/HTL interfaces improved charge carrier dynamics and reduced recombination losses, resulting in enhanced photovoltaic parameters across the board. (Scheme S1) Among these, the most notable improvements were in the V_oc, which significantly contributed to the overall enhancement in the photovoltaic performance of the PSCs.

To further investigate whether the device modification approach using tailored GQDs can effectively be applied to large-area modules, perovskite solar mini-modules were fabricated with a 25 cm² aperture area, consisting of five serially connected sub-cells. Figure 4A illustrates the I–V characteristics of top-performing module, with an inset showing photographic image of the module. Under 1 sun illumination, the module achieved a PCE of 18.91%, characterized by a V_oc of 5.33 V, an I_sc of 116.28 mA, and a FF of 76.27%.

As displayed in Figure 4B, the SPO measured at 4.27 V for 100 s delivered a stable PCE of 18.91%, closely aligning with the I–V scan results, thereby affirming the accuracy of the operational performance. Notably, Figure 4C highlights the high reproducibility observed in the module, demonstrated by a narrow PCE distribution averaging 16.93% ± 1.27% across 30 samples, with no observed device failures. This indicates that GQDs treatment can be effectively applied to module fabrication without additional processes. The PCE of the best-performing perovskite solar mini-module, along with the average photovoltaic parameters of 30 samples, is summarized in Table S3, with the distribution visualized in Figure S18.

To assess the long-term stability of the BiT module, the BiT perovskite solar mini-module was encapsulated and subjected to continuous 1 sun illumination under 25°C/35% relative humidity for 1000 h. The I–V curves recorded during this stability test are presented in Figure 4D, and the corresponding PCE changes over time are shown in Figure 4E. Detailed photovoltaic parameters before and after the stability test are provided in Table S3. The module maintained approximately ~89% of its initial PCE of 18.91%, indicating good photo-stability and reliable performance under prolonged light exposure.

4.1 Chemicals and Materials

For synthesizing GQDs, 1-hexanol (99%) was purchased from JUNSEI. D-(+)-Glucose, acetic acid (AC, ≥ 99.7%), BA, 99.5%, OA, 99%, and DDA, 98% were purchased from Sigma–Aldrich. Methanol (ME, 99.5%) was purchased from SAMCHUN CHEMICALS. For fabricating PSCs, the patterned indium-doped tin oxide (ITO)-coated conductive glass and encapsulation cover glass were purchased from 3H.

Ethanol (EA, 99.5%) and isopropanol (IPA, 99.5%) for substrate cleaning were purchased from SAMCHUN CHEMICALS. Tin (II) chloride dihydrate (SnCl₂2H₂O, ≥ 98%), N,N-dimethylformamide (DMF, 99.8%), dimethyl sulfoxide (DMSO, 99.8%) diethyl ether (DE, ≥ 99.0%), bis(trifluoromethane)sulfonamide lithium salt (Li-TFSI, 99.95%), 4-tert-butylpyridine (tBP, 96%), chlorobenzene (CB, 99.8%), and acetonitrile (ACN, 99.8%) were purchased from Sigma–Aldrich. Formamidinium iodide (FAI, 99.5%) and methylammonium chloride (MACl, 99.5%) were purchased from Yingkou Advanced Election Technology Co. Ltd. Lead (II) iodide (PbI₂, 99.9985%) was purchased from Alfa Aesar. 2,2′,7,7′-Tetrakis(N,N-di-pmethoxyphenylamino)-9,9′-spirobifluorene (Spiro-OMeTAD, 99.8%) was purchased from Lumtec. All chemicals were used as received without further purification.

4.2 Synthesis of Bespoke GQDs for PSCs

To synthesize GQDs, we first added 10 mL of 1-hexanol as the oil phase to a 25 mL 3-neck round-bottom flask and bubbled N₂ through it at an 80 cc/min flow rate for 1 h. Next, we introduced 1 mL of 10 wt.% aqueous glucose solution as the carbon source and 200 μL of AC as the catalyst for the Amadori rearrangement. The mixture was then aged at 80°C, with stirring at 1500 rpm in a closed system for 1 h. To tailor the properties of the GQDs, we added 3.3 mM of alkyl amine with various alkyl lengths, such as OA and DDA, and heated the reactor to 150°C under an 80 cc/min N₂ purged condition for 1 h at 1500 rpm. For short-length BA, solvothermal method was used because of its high volatility. The mixture was reacted at 80°C and 3.3 mM BA was placed in a 15 mL Teflon-lined stainless-steel autoclave, heated to 150°C, and stirred at 800 rpm for 1 h. To terminate the reaction, we rapidly combine the reaction mixture with 290 mL of ME. After mixing with ME, we subjected it to bath sonication for 1 h. To separate and purify the solution from residual amines, different methods were employed depending on the alkyl length of the amine. In the case of BA, a thermal evaporator was used to remove the residual amine, followed by redispersing in ME and repeating the process. Following this, the dried GQDs by heating oven were dispersed in the target solvent. For OA and DDA, a simple aggregation technique was adopted. The product mixture was stored in a fridge at temperatures ranging from −25°C to −35°C for over 12 h to promote the aggregation of aliphatic amines. Subsequently, the precipitate was discarded using a simple vacuum filtration process through a polyvinylidene fluoride (PVDF) filter. Afterward, dialysis (3.5 kDa) purification was performed with the sample dispersed in EA for 7 days. The samples were refrigerated until use. The supernatant was then redispersed in the target solvent via a distillation process for additional application.

4.3 Fabrication of PSCs With Tailored GQDs

To fabricate the PSCs with tailored GQDs, patterned ITO glasses were cleaned sequentially using detergent, deionized water, EA, and IPA in an ultrasonic bath. The substrates were then exposed to ultraviolet ozone for 15 min. The SnO₂ NPs solution, used for ETL deposition, was prepared following existing literature [29]. The solution was spin-coated onto the substrate at 5000 rpm for 60 s and annealed at 100°C for 30 min. To tailor the ETL properties, SnO₂ solutions with different GQDs wt.% were individually prepared. Specifically, a 20 wt.% GQDs stock solution was prepared by dispersing GQDs in water. The SnO₂ solution, which had a concentration of approximately 15 wt.%, was dispersed in a 1:2 water-to-IPA mixture. To achieve SnO₂ solutions containing 5wt.%, 10wt.%, and 15 wt.% GQDs, approximately 7,5, 15, and 23 μL of the GQDs solution were added to the 3 mL of SnO₂ solution, respectively. These mixtures were then spin-coated onto the SnO₂/ITO substrate using the same procedure as the initial SnO₂ layer. For the control device, the SnO₂ NPs solution was spin-coated again with the same process. The perovskite solution was prepared by dissolving 224 mg/mL of FAI, 599 mg/mL of PbI₂, and 17.6 mg of MACl in a DMF and DMSO mixture with an 8.5: 1.5 volume-to-volume solvent ratio. The perovskite layer was deposited onto the ETL using a two-step spin-coating process at 1000 rpm for 10 s, followed by 5000 rpm for 30 s. Approximately 10 s before the end of the spin-coating process, a toluene solution containing GQDs at various wt.% was dropped onto the substrate to induce antisolvent dripping crystallization [33] and surface passivation [30]. The GQDs stock solution used in this process was prepared by dispersing 30 wt.% GQDs in toluene. To prepare 10 wt.% and 20 wt.% GQDs toluene solutions, 16.7 and 33.6 μL of the 30 wt.% GQDs stock solution were added to 5 mL of toluene, respectively. After spin-coating, the substrate was annealed at 150°C for 30 min. The spiro-OMeTAD solution was prepared by dissolving 72.3 mg of spiro-OMeTAD in 1 mL of CB and adding 17.5 μL of Li-TFSI (520 mg dissolved in 1 mL of ACN) and 30 μL of tBP. The solution was spin-coated at 4000 rpm for 30 s. For the top electrode, a 60 nm Au layer was thermally deposited at a 2.0 Å/s evaporation rate.

4.4 Characterization of GQDs

TEM images were acquired using a TEM (Tecnai 20, FEI) operating at an accelerating voltage of 200 kV. TEM samples were prepared by placing ME-dispersed GQDs onto a copper grid (01800-F, Ted Pella). Raman spectra were acquired using a Raman spectrometer (LabRam ARAMIS IR2, HORIBA JOBIN YVON) with a 532 nm laser on a sample dropped onto glass. FT–IR spectra were collected using a FT–IR spectrometers with sample dispersed in KBr pellets. UV–Vis spectra were obtained using a UV–Vis spectrometer (UV-3600 Plus, Shimadzu) with the GQDs suspended in ME. PL and TRPL spectra were obtained using fluorospectrometer and photon counting spectrometers integrated within a single system (PC1, ISS). For the TRPL measurement, a 373 nm pulsed laser was utilized for excitation. UPS analysis was conducted by UPS system (Nexsa, Thermo Fisher) with He (21.22 eV) source.

4.5 Characterization of PSCs

The J-V curves were acquired using a source meter (Keithley 2420) under 1 sun illumination (100 mW/cm², AM 1.5G) from a solar simulator (Sun 3000, Abet technologies) equipped with a 1400 W Xenon lamp (#11044A, Abet technologies). The light intensity was calibrated using an NREL-certified Si solar cell (#15150, Abet technologies). EQE measurements were conducted using a power source featuring a 150 W Xenon lamp (#13014, Abet technologies), a monochromator (MonoRa-500i, DONGWOO OPTRON Co. Ltd.), and a potentiostat (IviumStat, IVIUM).