Volume 33, Issue 48 p. 30
Preparative Organic Chemistry
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Stereoselective Functionalization of Dithiolanes and Dithianes: The First Example of an Axial Trapping.

Antonella Capperucci

Antonella Capperucci

Dip. Chim. Org., Univ. Stud. Firenze, I-50019 Sesto Fiorentino, Italy

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Vanda Cere

Vanda Cere

Dip. Chim. Org., Univ. Stud. Firenze, I-50019 Sesto Fiorentino, Italy

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Alessandro Degl'Innocenti

Alessandro Degl'Innocenti

Dip. Chim. Org., Univ. Stud. Firenze, I-50019 Sesto Fiorentino, Italy

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Tiziano Nocentini

Tiziano Nocentini

Dip. Chim. Org., Univ. Stud. Firenze, I-50019 Sesto Fiorentino, Italy

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Salvatore Pollicino

Salvatore Pollicino

Dip. Chim. Org., Univ. Stud. Firenze, I-50019 Sesto Fiorentino, Italy

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First published: 18 May 2010

Abstract

For Abstract see ChemInform Abstract in Full Text.

ChemInform Abstract

The reaction of the trans silyldithiane (VIII) with benzaldehyde (II) using TBAF as fluoride ion source gives the adduct (IX) in which the electrophile is in the axial position.

chemical structure image

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