Volume 33, Issue 16
Preparative Organic Chemistry
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ChemInform Abstract: Silation of Alcohols and Aldehydes Catalyzed by Bisacetylacetonatochlorocyclopentadienylzirconium(IV).

Sock Sung Yun

Sock Sung Yun

Dep. Chem., Chungnam Natl. Univ., Taejon 305-764, S. Korea

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Jun Lee

Jun Lee

Dep. Chem., Chungnam Natl. Univ., Taejon 305-764, S. Korea

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Samkeun Lee

Samkeun Lee

Dep. Chem., Chungnam Natl. Univ., Taejon 305-764, S. Korea

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First published: 22 May 2010

Abstract

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ChemInform Abstract

Efficient O-silation of alcohols and aldehydes with phenylsilane furnishing trialkoxyphenylsilanes as main products is achieved under mild conditions using a ZrCl(Cp)(acac)2/tBuLi catalyst system.

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