ChemInform Abstract: Selective Radical Reactions in Multiphase Systems: Phase-Transfer Halogenations of Alkanes.
Abstract
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ChemInform Abstract
Haloalkanes are synthesized by selective radical reactions in multiphase systems from unactivated saturated hydrocarbones which may be linear, branched, polycyclic, strained and unstrained. The phase-transfer system avoids overfunctionalization of the products. The present new method is the only way for direct preparative iodination of alkanes.