Preparative Organic Chemistry
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ChemInform Abstract: Synthesis and Catalytic Properties of Configurationally Stable and Non-racemic Sulfur-Containing Palladacycles.
First published: 27 May 2010
Abstract
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ChemInform Abstract
The molecular structure of optically active Pd-complex (I) is determined by means of X-ray diffraction analysis. Its chloro-bridged analogue (II) is an excellent catalyst precursor for arylation of 3,4-dihydro-2H-pyran (III) under mild conditions but without any asymmetric induction.
