ChemInform Abstract: Total Synthesis of Marchantinquinone.
Abstract
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ChemInform Abstract
Key steps in the synthesis of title compound (IX) are the nucleophilic SNAr-reaction of an activated benzoate derivative such as (V) with the bibenzylphenyl ether (IV) to give the diether (VI) and a macrocyclization via a Ni-mediated intramolecular coupling reaction of dichloride (VII) under optimized conditions.