Volume 31, Issue 51
Natural Products
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ChemInform Abstract: Synthesis of (+)- and (-)-Ferruginol via Asymmetric Cyclization of a Polyene.

Masahiro Tada

Masahiro Tada

Lab. Bio-Org. Chem., Tokyo Univ. Agric. Technol., Fuchu, Tokyo 183, Japan

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Sei Nishiiri

Sei Nishiiri

Lab. Bio-Org. Chem., Tokyo Univ. Agric. Technol., Fuchu, Tokyo 183, Japan

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Yang Zhixiang

Yang Zhixiang

Lab. Bio-Org. Chem., Tokyo Univ. Agric. Technol., Fuchu, Tokyo 183, Japan

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Yumiko Imai

Yumiko Imai

Lab. Bio-Org. Chem., Tokyo Univ. Agric. Technol., Fuchu, Tokyo 183, Japan

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Shiho Tajima

Shiho Tajima

Lab. Bio-Org. Chem., Tokyo Univ. Agric. Technol., Fuchu, Tokyo 183, Japan

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Naoko Okazaki

Naoko Okazaki

Lab. Bio-Org. Chem., Tokyo Univ. Agric. Technol., Fuchu, Tokyo 183, Japan

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Yoshikazu Kitano

Yoshikazu Kitano

Lab. Bio-Org. Chem., Tokyo Univ. Agric. Technol., Fuchu, Tokyo 183, Japan

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Kazuhiro Chiba

Kazuhiro Chiba

Lab. Bio-Org. Chem., Tokyo Univ. Agric. Technol., Fuchu, Tokyo 183, Japan

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First published: 31 May 2010

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

ChemInform Abstract

Ferruginol (IV) is synthesized via a route involving the treatment of esters (I), (V), or (VII) with BF3×OEt2 to give either racemic or pure enantiomeric compound (IV), which by further elaboration is transformed to the target terpene.

chemical structure image

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